One-Step Synthesis of Monosilicon-Substituted Norbornenes with Siloxane and Aryl Fragments and Their Polymerization
- Authors: Guseva M.A.1, Lezhnin P.P.1, Alentiev D.A.1, Zaitsev K.V.1, Bermeshev M.V.1
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Affiliations:
- Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences
- Issue: Vol 65, No 2 (2023)
- Pages: 210-219
- Section:
- URL: https://journals.rcsi.science/2308-1147/article/view/232915
- DOI: https://doi.org/10.31857/S230811472370036X
- EDN: https://elibrary.ru/HKETWN
- ID: 232915
Cite item
Abstract
Three monosilicon-substituted norbornene monomers with phenyl and siloxane groups at the silicon atom are synthesized by the one-step hydrosilylation of 2,5-norbornadiene. The proposed method allows the synthesis of monomers with a higher content of polymerization-reactive exo-isomer in products compared with similar adducts formed by the Diels‒Аlder reaction. The synthesized monomers show high reactivity in both metathesis polymerization and addition polymerization more sensitive to the substituent volume. Using these monomers two series of high molecular weight silicon-substituted polynorbornenes are prepared which are found to be glassy and thermally stable polymers.
About the authors
M. A. Guseva
Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences
Email: d.alentiev@ips.ac.ru
119991, Moscow, Russia
P. P. Lezhnin
Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences
Email: d.alentiev@ips.ac.ru
119991, Moscow, Russia
D. A. Alentiev
Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences
Email: d.alentiev@ips.ac.ru
119991, Moscow, Russia
K. V. Zaitsev
Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences
Email: d.alentiev@ips.ac.ru
119991, Moscow, Russia
M. V. Bermeshev
Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences
Author for correspondence.
Email: d.alentiev@ips.ac.ru
119991, Moscow, Russia
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