Functionalized Oligoaryloxycyclotriphosphazenes and Noncombustible Binders Based on Them
- Authors: Bilichenko Y.V.1, Thuan P.V.1, Borisov R.S.1,2, Kolenchenko A.A.1, Kireev V.V.1
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Affiliations:
- Mendeleev University of Chemical Technology
- Topchiev Institute of Petrochemical Synthesis
- Issue: Vol 65, No 2 (2023)
- Pages: 158-163
- Section:
- URL: https://journals.rcsi.science/2308-1147/article/view/232903
- DOI: https://doi.org/10.31857/S2308114723700346
- EDN: https://elibrary.ru/HYBZXK
- ID: 232903
Cite item
Abstract
Carboxyl-containing aryloxycyclotriphosphazene (I) has been used for curing the ED-20 epoxy resin or a phosphazene-containing epoxy oligomer. In the case of ED-20, curing occurs in the range of 125‒220°C and is accompanied by an exothermic effect that increases from 26 to 50 J/g with an increase in the amount of aryloxycyclotriphosphazene (I) from 25 to 50%. The curing of the phosphazene-containing epoxy oligomer occurs in the temperature range of 140–240°C and is accompanied by an endothermic effect (−ΔH = 6.5–6.8 J/g). Cured compositions based on ED-20 + I are self-extinguishing (flammability class V‑1 according to UL-94), and phosphazene-containing epoxy oligomer + I compositions are noncombustible (class V-0 according to UL-94) regardless of the ratio of the initial components.
About the authors
Yu. V. Bilichenko
Mendeleev University of Chemical Technology
Email: kireev.v.v@muctr.ru
125047, Moscow, Russia
Pham Van Thuan
Mendeleev University of Chemical Technology
Email: kireev.v.v@muctr.ru
125047, Moscow, Russia
R. S. Borisov
Mendeleev University of Chemical Technology; Topchiev Institute of Petrochemical Synthesis
Email: kireev.v.v@muctr.ru
125047, Moscow, Russia; 119991, Moscow, Russia
A. A. Kolenchenko
Mendeleev University of Chemical Technology
Email: kireev.v.v@muctr.ru
125047, Moscow, Russia
V. V. Kireev
Mendeleev University of Chemical Technology
Author for correspondence.
Email: kireev.v.v@muctr.ru
125047, Moscow, Russia
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