Structural Changes during Polymerization of Acrylamide in Semidilute Solutions of Wormlike Surfactant Micelles

A. S. Ospennikov; Оспенников А. С.; A. V. Shibaev; Шибаев А. В.; A. I. Kuklin; Куклин А. И.; O. E. Philippova; Филиппова О. Е.

doi:10.31857/S2308112023600060

Structural Changes during Polymerization of Acrylamide in Semidilute Solutions of Wormlike Surfactant Micelles

Autores: Ospennikov A.¹, Shibaev A.¹, Kuklin A.²^,3, Philippova O.¹
Afiliações:
1. Faculty of Physics, Moscow State University
2. Joint Institute for Nuclear Research
3. Moscow Institute of Physics and Technology
Edição: Volume 65, Nº 5 (2023)
Páginas: 327-332
Seção: РАСТВОРЫ
URL: https://journals.rcsi.science/2308-1120/article/view/233616
DOI: https://doi.org/10.31857/S2308112023600060
EDN: https://elibrary.ru/DBWHGH
ID: 233616

Citar

Texto integral

Acesso aberto
Acesso é fechado

Acesso está concedido
Acesso é fechado

Somente assinantes

Resumo
Sobre autores
Bibliografia
Arquivos suplementares
Estatísticas

Resumo

The structure and rheological properties of aqueous solutions of the anionic surfactant potassium oleate and the water-soluble monomer acrylamide before and after radical polymerization have been studied. In the absence of monomer and in the presence of a low-molecular-weight salt, potassium oleate forms a network of long entangled cylindrical (wormlike) micelles. The addition of the monomer does not lead to a change in their cylindrical shape and radius, but it promotes the transformation of branched micelles into linear ones. The structure of surfactant aggregates changes significantly after polymerization: according to neutron scattering data, it becomes bicontinuous and its local geometry becomes lamellar. The coexistence of such a structure with polyacrylamide macromolecules in a semidilute solution leads to a significant synergistic increase in viscosity and elastic modulus.

Bibliografia

Семчиков Ю.Д. Высокомолекулярные соединения. М.: Академия, 2008.
Gur’eva L.L., Tkachuk A.I., Estrin Ya.i., Komarov B.A., Dzhavadyan E.A., Estrina G.A., Bogdanova L.M., Surkov N.F., Rozenberg B.A. // Polymer Science A. 2008. V. 50. № 3. P. 283.
Kulichikhin S.G., Malkin A.Ya., Polushkina O.M., Kulichikhin V.G. // Polym. Eng. Sci. 1997. V. 37. № 8. P. 1331.
Fischer E.J., Storti G., Cuccato D. // Processes. 2017. V. 5. № 2. P. 23.
Jaeger W., Hahn M., Lieske A., Zimmermann A., Brand F. // Macromol. Symp. 1996. V. 111. № 1. P. 95.
Evans F.D., Wennerström H. The Colloidal Domain: Where Physics, Chemistry, Biology, and Technology Meet. New York: Wiley-VCH, 1999.
Hill A., Candau F., Selb J. // Macromolecules. 1993. V. 26. № 17. P. 4521.
Candau F., Biggs S., Hill A., Selb J. // Prog. Org. Coat. 1994. V. 24. № 1–4. P. 11.
Friend J.P., Alexander A.E. // J. Polym. Sci., Polym. Chem. 1968. V. 6. P. 1833.
Niranjan P.S., Tiwari A.K., Upadhyay S.K. // J. Appl. Polym. Sci. 2011. V. 122. P. 981.
Barthet C., Wilson J., Cadix A., Destarac M., Chassenieux C., Harrisson S. // J. Polym. Sci., Polym. Chem. 2018. V. 56. № 7. P. 760.
Sabbadin J., François J. // Colloid Polym. Sci. 1980. V. 258. P. 1250.
Dreiss C.A. // Soft Matter. 2007. V. 3. № 8. P. 956.
Shibaev A.V., Osiptsov A.A., Philippova O.E. // Gels. 2021. V. 7. № 4. P. 258.
Israelachvili J.N., Mitchell D.J., Ninham B.W. // J. Chem. Soc., Faraday Trans. 2. 1976. V. 72. P. 1525.
Bergström L.M. // AIP Adv. 2018. V. 8. № 5. P. 055136.
Can V., Kochovski Z., Reiter V., Severin N., Siebenburger M., Kent B., Just J., Rabe J.P., Ballauf M., Okay O. // Macromolecules. 2016. V. 49. № 6. P. 2281.
Tuncaboylu D.C., Sari M., Oppermann W., Okay O. // Macromolecules. 2011. V. 44. № 12. P. 4997.
Shibaev A.V., Ospennikov A.S., Kuznetsova E.K., Kuklin A.I., Aliev T.M., Novikov V.V., Philippova O.E. // Nanomaterials. 2022. V. 12. P. 4445.
Shibaev A.V., Smirnova M.E., Kessel D.E., Bedin S.A., Razumovskaya I.V., Philippova O.E. // Nanomaterials. 2021. V. 11. P. 1271.
Roland S., Miquelard-Garnier G., Shibaev A.V., Aleshina A.L., Chennevière A., Matsarskaia O., Sollogoub C., Philippova O.E., Iliopoulos I. // Polymers. 2021. V. 13. P. 4255.
Shibaev A.V., Aleshina A.L., Arkharova N.A., Orekhov A.S., Kuklin A.I., Philippova O.E. // Nanomaterials. 2020. V. 10. № 12. P. 2353.
Molchanov V.S., Philippova O.E. // Colloid J. 2009. V. 71. № 2. P. 239.
Calabrese M.A., Wagner N.J. // ACS Macro Lett. 2018. V. 7. № 6. P. 614.
Lequeux F. // Europhys. Lett. 1992. V. 19. P. 675.
Ospennikov A.S., Gavrilov A.A., Artykulnyi O.P., Kuklin A.I., Novikov V.V., Shibaev A.V., Philippova O.E. // J. Colloid Interface Sci. 2021. V. 602. P. 590.
Oelschlaeger C., Schopferer M., Scheffold F., Willenbacher N. // Langmuir. 2009. V. 25. № 2. P. 716.
Grillo I. // Soft Matter Characterization / Ed. by R. Borsali, R. Pecora. Springer, 2008. P. 723.
Li X., Lin Z., Cai J., Scriven L.E., Davis H.T. // J. Phys. Chem. 1995. V. 99. P. 10865.
Shibaev A.V., Kuklin A.I., Torocheshnikov V.N., Ore-khov A.S., Roland S., Miquelard-Garnier G., Matsarskaia O., Iliopoulos I., Philippova O.E. // J. Colloid Interface Sci. 2022. V. 611. P. 46.
Gamez-Corrales R., Berret J.-F., Walker L.M., Oberdisse J. // Langmuir. 1999. V. 15. P. 6755.
Salentinig S., Sagalowicz L., Glatter O. // Langmuir. 2010. V. 26. № 14. P. 11670.