Conductometric and Potentiometric Titration of Carboxyl Groups in Polymer Microspheres
- 作者: Shestakova D.O.1,2, San’kova N.N.2, Parkhomchuk E.V.1,2
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隶属关系:
- Novosibirsk State University
- Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences
- 期: 卷 65, 编号 5 (2023)
- 页面: 391-404
- 栏目: МЕТОДЫ ИССЛЕДОВАНИЯ
- URL: https://journals.rcsi.science/2308-1120/article/view/233628
- DOI: https://doi.org/10.31857/S2308112023600102
- EDN: https://elibrary.ru/DCZBWT
- ID: 233628
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详细
A laboratory procedure has been suggested for determining the concentration of carboxyl groups at the surface of polystyrene microspheres at the latex concentration of a few hundredths of weight percentage (the COOH groups concentration below 4 × 10−4 mol/L). The procedure is based on conductometric and potentiometric titration. The influence of polymer particles concentration in the system, ionic strength of the solution, titration duration, and the system inertness on the obtained values of the carboxyl groups concentration and the determination accuracy have been investigated.
作者简介
D. Shestakova
Novosibirsk State University; Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences
Email: d.shestakova@g.nsu.ru
630090, Novosibirsk, Russia; 630090, Novosibirsk, Russia
N. San’kova
Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences
Email: d.shestakova@g.nsu.ru
630090, Novosibirsk, Russia
E. Parkhomchuk
Novosibirsk State University; Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences
编辑信件的主要联系方式.
Email: d.shestakova@g.nsu.ru
630090, Novosibirsk, Russia; 630090, Novosibirsk, Russia
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