Methacrylate Single-Ion Conducting Block Copolymers: Effect of the Chemical Structure on Conductivity and Morphological Organization

Cover Page

Cite item

Full Text

Open Access Open Access
Restricted Access Access granted
Restricted Access Subscription Access

Abstract

A series of novel anionic block copolymers, in which the neutral block is formed by 2-phenylethyl methacrylate (PEM) and the ionic block is prepared via statistical copolymerization of lithium 1-[3-(methacryloyloxy)-propylsulfonyl]-1-(trifluoromethanesulfonyl)imide (LiM) and methyl ether of poly(ethylene glycol) methacrylate (PEGM) have been synthesized. The effects of chemical structure, composition, and molecular mass of the blocks on ionic conductivity and thermal properties of the poly[PEM–block–(LiM–stat–PEGM)] block copolymers have been investigated. It has been found by means of small-angle X-ray scattering that the introduction of a small fraction of the lithium-containing units (~7 mol %) in the structure of neutral poly[PEM–block–PEGM] copolymer leads to microphase separation and ordering of the system. Combined small-angle X-ray scattering and atomic force microscopy data have evidenced the formation of lamellar structure with the interplanar distance of d ~ 28 nm.

About the authors

E. I. Lozinskaya

A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences (INEOS RAS)

Email: helloz@ineos.ac.ru
119334, Moscow, Russia

D. O. Ponkratov

A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences (INEOS RAS)

Email: helloz@ineos.ac.ru
119334, Moscow, Russia

A. S. Shaplov

Luxembourg Institute of Science and Technology

Email: helloz@ineos.ac.ru
L-4362, Esch-sur-Alzette, Luxembourg

I. A. Malyshkina

Department of Physics, Moscow State University (MSU)

Email: helloz@ineos.ac.ru
119991, Moscow, Russia

D. R. Streltsov

Enikolopov Institute of Synthetic Polymer Materials, Russian Academy of Sciences

Email: helloz@ineos.ac.ru
117393, Moscow, Russia

A. V. Bakirov

Enikolopov Institute of Synthetic Polymer Materials, Russian Academy of Sciences

Author for correspondence.
Email: helloz@ineos.ac.ru
117393, Moscow, Russia

References

  1. Armand M., Axmann P., Bresser D., Copley M., Edström K., Ekberg Ch., Guyomard D., Lestriez B., Nov’ak P., Petranikova M., Porche W., Trabesinger S., Wohlfahrt-Mehrens M., Zhang H. // J. Power Sources. 2020. V. 479. P. 228708.
  2. Manthiram A. // Nat. Commun. 2020. V. 11. P. 1550.
  3. Zhang H., Li Ch., Piszcz M., Coya E., Rojo T., Rodriguez-Martinez L.M., Armand M., Zhou Z. // Chem. Soc. Rev. 2017. V. 46. № 3. P. 797
  4. Ibrahim H., Ilinca A., Perron J. // Renew. Sustain. Energy Rev. 2008. V. 12. № 5. P. 1221.
  5. Xu K. // Chem. Rev. 2004. V. 104. № 10. P. 4303.
  6. Hammami A., Raymond N., Armand M. // Nature. 2003. V. 424. № 6949. P. 635.
  7. Voropaeva D.Yu., Novikova S.A., Yaroslavtsev A.B. // Russ. Chem. Rev. 2020. V. 89. № 10. P. 1132.
  8. Jiang Y., Yan X., Ma Zh., Mei P., Xiao W., You Q., Zhang Y. // Polymers. 2018. V. 10. № 11. P. 1237.
  9. Forsyth M., Porcarelli L., Wang X., Goujon N., Mecerreyes D. // Acc. Chem. Res. 2019. V. 52. № 3. P. 686.
  10. Fergus J.W. // J. Power Sources. 2010. V. 195. № 15. P. 4554.
  11. Sua T.-T., Le J.-B., Ren W.-F., Zhang Sh.-J., Yuan J.-M., Wang K., Shao Ch.-Y., Li J.-T., Sun Sh.-G., Sun R.-C. // J. Power Sources. 2022. V. 521. P. 230949.
  12. Mauger A., Julien C.M., Goodenough J.B., Zaghib K. // J. Electrochem. Soc. 2020. V. 167. № 7. P. 070507.
  13. Chen G., Niu Ch., Chen Y., Shang W., Qu Y., Du Zh., Zhao L., Liao X., Du J., Chen Y. // Solid State Ionics. 2019. V. 341. P. 115048.
  14. Bouchet R., Maria S., Meziane R., Aboulaich A., Lienafa L., Bonnet J.-P., Phan T.N.T., Bertin D., Gigmes D., Devaux D., Denoyel R., Armand M. // Nat. Mater. 2013. V. 12. P. 452.
  15. Zhang Y., Lim C.A., Cai W., Rohan R., Xu G., Sun Y., Cheng H. // RSC Adv. 2014. V. 4. № 83. P. 43857.
  16. Jangu C., Savage A.M., Zhang Z., Schultz A.R., Madsen L.A., Beyer F.L., Long T.E. // Macromolecules. 2015. V. 48. № 13. P. 4520.
  17. Long L., Wang Sh., Xiao M., Meng Y. // J. Mater. Chem. A. 2016. V. 4. № 26. P. 10038.
  18. Ma Q., Zhang H., Zhou C., Zheng L., Cheng P., Nie J., Feng W., Hu Y.-S., Li H., Huang X., Chen L., Armand M., Zhou Z. // Angew. Chem. Int. Ed. 2016. V. 55. № 7. P. 2521.
  19. Elmore C.T., Seidler M.E., Ford H.O., Merrill L.C., Upadhyay S.P., Schneider W.F., Schaefer J.L. // Batteries. 2018. V. 4. № 2. P. 28.
  20. Zhang M., Yu S., Mai Y., Zhang Sh., Zhou Y. // Chem. Commun. 2019. V. 55. P. 6715.
  21. Zhang B., Zheng C., Sims M.B., Bates F.S., Lodge T.P. // ACS Macro Lett. 2021. V. 10. P. 1035.
  22. Shim J., Bates F.S., Lodge T.P. // Nat. Commun. 2019. V. 10. P. 2108.
  23. Pantazidis C., Andreou S., Nikolakakou G., Glynos E., Sakellariou G. // Polym. Chem. 2022. V. 13. № 14. P. 1997.
  24. Lingua G., Grysan P., Vlasov P.S., Verge P., Shaplov A.S., Gerbaldi C. // Macromolecules. 2021. V. 54. P. 6911.
  25. Lozinskaya E.I., Ponkratov D.O., Malyshkina I.A., Grysan P., Lingua G., Gerbaldi C., Shaplov A.S., Vygodskii Y.S. // Electrochim. Acta. 2022. V. 413. P. 140126.
  26. Porcarelli L., Shaplov A.S., Bella F., Nair J.R., Mecerreyes D., Gerbaldi C. // ACS Energy Lett. 2016. V. 1. № 4. P 678.
  27. Porcarelli L., Shaplov A.S., Salsamendi M., Nair J.R., Vygodskii Y.S., Mecerreyes D., Gerbaldi C. // ACS Appl. Mater. Interfaces. 2016. V. 8. № 16. P 10350.
  28. Porcarelli L., Aboudzadeh M.A., Rubatat L., Nair J.R., Shaplov A.S., Gerbaldi C., Mecerreyes D. // J. Power Sources. 2017. V. 364. P. 191.
  29. Sadoway D.R. // J. Power Sources. 2004. V. 129. P. 1.
  30. Chen T.-L., Sun R., Willis C., Morgan B.F., Beyer F.L., Elabd Y.A. // Polymer. 2019. V. 161. P. 128.
  31. Bouchet R., Phan T.N.T., Beaudoin E., Devaux D., Davidson P., Bertin D., Denoyel R. // Macromolecules. 2014. V. 47. № 8. P. 2659.
  32. Singh M., Odusanya O., Wilmes G.M., Eitouni H.B., Gomez E.D., Patel A.J., Chen V.L., Park M.J., Fragouli P., Iatrou H., Hadjichristidis N., Cookson D., Balsara N.P. // Macromolecules. 2007. V. 40. № 13. P. 4578.
  33. Chen T.-L., Lathrop P.M., Sun R., Elabd Y.A. // Macromolecules. 2021. V. 54. № 18. P. 8780.
  34. Abetz V., Goldacker T. // Macromol. Rapid Commun. 2000. V. 21. № 1. P. 16.
  35. Matsen M.W., Thompson R.B. // J. Chem. Phys. 1999. V. 111. № 15. P. 7139.
  36. Ye Y., Choi J.-H., Winey K.I., Elabd Y.A. // Macromolecules. 2012. V. 45. № 17. P. 7027.
  37. Weber R.L., Ye Y., Schmitt A.L., Banik S.M., Elabd Y.A., Mahanthappa M.K // Macromolecules. 2011. V. 44. № 14, 5727.
  38. Moad G., Rizzardo E., Thang S.H. // Aust. J. Chem. 2012. V. 65. № 8. P. 985.
  39. Moad G., Rizzardo E., Thang S.H. // Mater. Matters. 2010. V. 5. № 1. P. 2.
  40. Perrier S. // Macromolecules. 2017. V. 50. № 19. P. 7433.
  41. Keddie D.J. // Chem. Soc. Rev. 2014. V. 43. № 2. P. 496.
  42. Chernikova E.V., Sivtsov E.V. // Polymer Science B. 2017. V. 59. № 2. P. 117.
  43. Osada I., deVries H., Scrosati B., Passerini S. // Angew. Chem. Int. Ed. 2016. V. 55. № 2. P. 500.
  44. Sinha K., Wang W., Winey K.I., Maranas J.K. // Macromolecules. 2012. V. 45. № 10. P. 4354.
  45. Ярмоленко О.В., Хатмуллина К.Г. // Альтернативная энергетика и экология. 2010. Т. 3. № 83. С. 59.
  46. Nečas D., Klapetek P. // Cent. Eur. J. Phys. 2012. V. 10. № 1. P. 181.
  47. Lowe A.B. // Polymer. 2016. V. 106. P. 161.
  48. Pei Y., Lowe A.B. // Polym. Chem. 2014. V. 5. № 7. P. 2342.
  49. Lee H., Tae G., Kim Y.H. // Macromol. Res. 2008. V. 16. № 7. P. 614.
  50. Bates F.S. // Science. 1991. V. 251. № 4996. P. 898.
  51. Sing C., Zwanikken J., Olvera de la Cruz M. // Nature Mater. 2014. V. 13. P. 694.
  52. Meek K.M., Elabd. Y.A. // J. Mater. Chem. A. 2015. V. 3. № 48. P. 24187.
  53. Meek K.M., Sharick S., Ye Y., Winey K.I., Elabd Y.A. // Macromolecules. 2015. V. 48. № 14. P. 4850.

Supplementary files


Copyright (c) 2023 Е.И. Лозинская, Д.О. Понкратов, А.С. Шаплов, И.А. Малышкина, Д.Р. Стрельцов, А.В. Бакиров

This website uses cookies

You consent to our cookies if you continue to use our website.

About Cookies