Email this article Enthalpy of formation of the trinitromethyl group
- Authors: Miroshnichenko E.A.1, Kon’kova Т.S.1, Shastin A.V.2, Vorob’ev A.B.1, Inozemtsev J.O.1, Inozemtsev A.V.1, Matyushin Y.N.1, Korsunskiy B.L.1,2
-
Affiliations:
- N. N. Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences
- Federal Research Center for Problems of Chemical Physics and Medicinal Chemistry of the Russian Academy of Sciences
- Issue: Vol 16, No 3 (2023)
- Pages: 124-130
- Section: Articles
- URL: https://journals.rcsi.science/2305-9117/article/view/290014
- DOI: https://doi.org/10.30826/CE23160312
- EDN: https://elibrary.ru/RWYFCC
- ID: 290014
Cite item
Open Access
Access granted
Subscription Access
Abstract
The enthalpies of combustion and enthalpies of formation of three trinitromethyl derivatives of 1,3,5-triazine were determined by the calorimetric method. The data obtained can be used for calculating the energy capabilities of related compounds by the method of replacing functional groups. The thermochemical characteristics of trinitromethyl groups from 1,3,5-triazine derivatives are compared with the corresponding properties of these groups in azoles and nitroalkanes.
About the authors
Eugeny A. Miroshnichenko
N. N. Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences
Author for correspondence.
Email: eamir02@mail.ru
Doctor of Science in chemistry, chief research scientist
Russian Federation, MoscowТatiana S. Kon’kova
N. N. Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences
Email: tas-kon@mail.ru
Doctor of Science in chemistry, chief research scientist
Russian Federation, MoscowAleksey V. Shastin
Federal Research Center for Problems of Chemical Physics and Medicinal Chemistry of the Russian Academy of Sciences
Email: shastin@icp.ac.ru
Doctor of Science in chemistry, leading research scientist
Russian Federation, Chernogolovka, Moscow RegionAlexey B. Vorob’ev
N. N. Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences
Email: vectr1@yandex.ru
Candidate of Science in technology, senior research scientist
Russian Federation, MoscowJaroslav O. Inozemtsev
N. N. Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences
Email: vectr1@yandex.ru
senior research scientist
Russian Federation, MoscowAlexey V. Inozemtsev
N. N. Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences
Email: vectr1@yandex.ru
research scientist
Russian Federation, MoscowYuriy N. Matyushin
N. N. Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences
Email: ynm07@mail.ru
Doctor of Science in technology, head of laboratory
Russian Federation, MoscowBoris L. Korsunskiy
N. N. Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences; Federal Research Center for Problems of Chemical Physics and Medicinal Chemistry of the Russian Academy of Sciences
Email: vectr1@yandex.ru
Doctor of Science in chemistry, chief research scientist
Moscow; Chernogolovka, Moscow RegionReferences
- Shastin, A. V., T. I. Godovikova, and B. L. Korsunskiy. 2003. Nitro derivatives of 1,3,5-triazine: Synthesis and properties. Russ. Chem. Rev. 72(3):279–287. doi: 10.1070/RC2003v072n03ABEH000803.
- Zyuzin, I. N., I. Yu. Gudkova, and D. B. Lempert. 2020. The energy capabilities of new derivatives of 1,2,4- and 1,3,4-oxadiazoles as components of solid composite propellants. Russ. J. Phys. Chem. B 14(2):302–313. doi: 10.1134/S1990793120020062.
- Stepanov, R. S., L. A. Kruglyakova, and A. M. Astakhov. 2007. Effect of the structure of cyclic -nitramines on the rate and mechanism of their thermolysis. Russ. J. Gen. Chem. 77(11):1293–1299. doi: 10.1134/ S1070363207070237.
- Shastin, A. V., T. I. Godovikova, and B. L. Korsunskiy. 2011. A new method for the synthesis of 2,4-diazido-6-trinitromethyl-1,3,5- triazine. Russ. Chem. B. 60(6):1220–1222. doi: 10.1007/s11172-011-0191-y.
- Inozemtsev, Ya. O., A. B. Vorobyev, A. V. Inozemtsev, and Yu. N. Matyushin. 2014. Kalorimetriya energoemkikh soedineniy [Calorimetry of energetic materials]. Goren. Vzryv (Mosk.) — Combustion and Explosion 7:260–270.
- Kon’kova, T. S., Yu. N. Matyushin, E. A. Miroshnichenko, and A. B. Vorob’ev . 2009. Thermochemical properties of dinitramidic acid salts. Russ. Chem. B 58(10):2020–2027. doi: 10.1007/s11172-009-0276-z.
- Skuratov, S. M., V. P. Kolesov, and A. F. Vorob’ev. 1966. Termokhimiya [Thermochemistry]. Moscow: Moscow University. Part II. 302 p.
- Miroshnichenko, E. A., V. P. Lebedev, and Yu. N. Matyushin. 2002. Energy properties of adamantane derivatives. Dokl. Phys. Chem. 382(4-6):40–42. doi: 10.1023/ A:1014499229527.
- Huynh, M.-H. V., M. A. Hiskey, E. L. Hartline, D. P. Montoya, and R. Gilardi. 2004. Polyazido high-nitrogen compounds: Hydrazo-and azo-1,3,5-triazine. Angew. Chem. Int. Edit. 43(37):4924–4928. doi: 10.1002/ anie.200460366.
- Shastin, A. V., T. I. Godovikova, S. P. Golova, L. I. Khmel’nitskii, and B. L. Korsunskii. 1995. Nucleophilic substitution reactions of 2,4,6-tris(trinitromethyl)-1,3,5-triazine. 1. Interaction of 2,4,6-tris(trinitromethyl)-1,3,5-triazine with alcohols, diols, ammonia, and secondary amines. Chem. Heterocyc. Compd. 31:596–600. doi: 10.1007/BF01166337.
- Shastin, A. V., T. I. Godovikova, S. P. Golova, L. I. Khmel’nitskii, and B. L. Korsunskii. 1995. Nucleophilic substitution reactions of 2,4,6-tris(trinitromethyl)-1,3,5-triazine. 2. Interaction of 2,4,6-tris(trinitromethyl)-1,3,5-triazine with primary amines and hexamethyldisilazane. Chem. Heterocyc. Compd. 31:601–609. doi: 10.1007/BF01166338.
- Shastin, A. V., and D. B. Lempert. 2016. Enthalpies of formation of trinitromethyl-substituted aromatic and heteroaromatic compounds and their efficiency as oxidizers in energetic compositions. Russ. J. Phys. Chem. B 10(4):632–638. doi: 10.1134/S1990793116040266.
Supplementary files
