Energetic potential of tris(pyrrolo)-, tris(diazolo)benzenes, and 1,3,5-azines as model components of solid propellants

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Дәйексөз келтіру

Толық мәтін

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Рұқсат жабық Тек жазылушылар үшін

Аннотация

Enthalpies of formation of a number of hypothetical tris(pyrrolo)- and tris(diazolo)benzenes and 1,3,5-azines in the condensed phase have been estimated on the basis of calculated values of enthalpies of formation of these compounds in the gas phase. Their efficiency as components (main energetic component or binder plasticizer) of model solid composite propellants or as energetic component for increasing ballistic efficiency of nonmetallized solid propellants for gas-generator engines has been analyzed. It has been established that polynitro-derivatives of the proposed pyrrole-, pyrazole-, and imidazole-containing tetracycles can be used as plasticizers of the active binder in the compositions of model solid composite propellants including those based on aluminum hydride, metallic aluminum, and those without metal providing higher ballistic efficiency on all three stages of rocket systems in comparison with similar propellants using the most promising modern plasticizers, for example, dinitrofurazan, nitroglycerin, or tetranitromethane. It is shown by calculations that the studied tetracycles which do not contain nitro groups can serve as high-enthalpy components in propellants for gas generator engines providing high ballistic efficiency relative to the binary formulation of a dispersant with rubber.

Толық мәтін

Рұқсат жабық

Авторлар туралы

Vladimir Parakhin

N.D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences

Хат алмасуға жауапты Автор.
Email: parakhin@ioc.ac.ru

Candidate of Sciences in Chemistry, Senior Researcher

Ресей, Moscow

Vadim Volokhov

Federal Research Center for Problems of Chemical Physics and Medicinal Chemistry of the Russian Academy of Sciences

Email: vvm@icp.ac.ru

Doctor of Sciences in Physics and Mathematics, Professor, Chief Researcher

Ресей, Chernogolovka

David Lempert

Federal Research Center for Problems of Chemical Physics and Medicinal Chemistry of the Russian Academy of Sciences

Email: lempert@icp.ac.ru

Candidate of Sciences in Chemistry, Chief Researcher

Ресей, Chernogolovka

Elena Amosova

Federal Research Center for Problems of Chemical Physics and Medicinal Chemistry of the Russian Academy of Sciences

Email: aes@icp.ac.ru

Researcher

Ресей, Chernogolovka

Vladimir Voevodin

Lomonosov Moscow State University

Email: voevodin@parallel.ru

Doctor of Sciences in Physics and Mathematics, Corresponding Member of the Russian Academy of Sciences, Professor, Director of the Research Computing Center

Ресей, Moscow

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2. Fig. 1. Structures of the objects of the study — energetic tris(pyrrolo)-, tris(diazolo)benzenes, and 1,3,5-azines

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3. Fig. 2. The Ief(2) (a) and Ief(3) (b) values of formulations containing 27% (vol.) PMVT (polymethylvinyl tatrazole) binder/plasticizer = 1 : 4 (IIa, IIb, IVa, IVb, VIa–VIc, DNF (dinitrofurazane), NG (nitroglycerin), or ТNМ (tetranitromethane)), 25% (wt.) aluminum hydride and ammonium dinitramide (ADN) (rest)

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4. Fig. 3. The Ief(1) (a), Ief(2) (b), and Ief(3) (c) values of formulations containing 50% (wt.) HMX, 19% (vol.) PMVT binder/plasticizer = 1 : 4 (IIa, IIb, IVa, IVb, VIa–VIc, DNF, NG, or ТNМ), 15% (wt.) Al, and ammonium perchlorate (AP) (rest)

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5. Fig. 4. The Ief(1) (a), Ief(2) (b), and Ief(3) (c) values of formulations containing 50% (wt.) HMX, 19% (vol.) PMVT binder/plasticizer = 1 : 4 (IIa, IIb, IVa, IVb, VIa–VIc, DNF, NG, or ТNМ), and AP (rest)

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6. Fig. 5. Dependence of Qv(1500) values of propellant compositions containing rubber SKI-3, Az(O)NH2, and high-enthalpy component (HEC) Ia (1), Ib (2), IIIa (3), IIIb (4), Va (5), and Vb (6) at Tad = 1500 ± 5 K as well as dicyanobenzene (7), phenazine-N-oxide (8), naphtacene (9), and anthracene (10) on the nature of the HEC and its mass content

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