INVESTIGATION OF ACOUSTIC, OPTICAL AND PHOTOREFRACTIVE PROPERTIES OF MULTICRYSTALS OF LITHIUM NIOBATE DOPED WITH ZINC IN THE AREA OF CONCENTRATIONS OF 5,38-9,0 MOL.% Zn

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Abstract

Obtaining optical materials based on lithium niobate with controlled optical properties is an important task of modern materials science. To date the problem of obtaining heavily doped LiNbO3 crystals of optical quality with a macroscopically uniform impurity distribution has not been solved. In this work a comparative analysis of studies of the acoustic, optical and photorefractive properties of LiNbO 3: Zn lithium niobate single crystals obtained by direct and homogeneous doping from melts with concentrations of 5,38-9,0 mol% Zn has been carried out. The following methods have been used: piezoacoustics, photoinduced light scattering and laser conoscopy. The values of the static piezoelectric modulus have been determined. According to these values, all crystals are single-domain. Studies of crystals have confirmed the absence of a photorefractive effect in them. It was established that LiNbO 3: Zn crystals grown on the basis of the method of homogeneous doping with concentrations in the melt of 6,8-9,0 mol% Zn are characterized by the highest structural and optical uniformity. This is of interest for the technology of growing large zinc-doped lithium niobate crystals by the Czochralski method.

About the authors

Ilya N. Efremov

Tananaev Institute of Chemistry - Subdivision of the Federal Research Centre «Kola Science Centre of the Russian Academy of Sciences»

Apatity, Russia

Sofia M. Masloboeva

Tananaev Institute of Chemistry - Subdivision of the Federal Research Centre «Kola Science Centre of the Russian Academy of Sciences»

Email: sofia_masloboeva@mail.RUS
Apatity, Russia

Irina V. Biryukova

Tananaev Institute of Chemistry - Subdivision of the Federal Research Centre «Kola Science Centre of the Russian Academy of Sciences»

Apatity, Russia

Natalya A. Teplyakova

Tananaev Institute of Chemistry - Subdivision of the Federal Research Centre «Kola Science Centre of the Russian Academy of Sciences»

Apatity, Russia

Mikhail N. Palatnikov

Tananaev Institute of Chemistry - Subdivision of the Federal Research Centre «Kola Science Centre of the Russian Academy of Sciences»

Apatity, Russia

References

  1. Furukawa, Y. Optical damage resistance and crystal quality of LiNbO3 single crystals with various [Li]/[Nb] ratios / Y. Furukawa, M. Sato, K. Kitamura et al. // The Journal of Applied Physics. - 1992. - V. 72. - I. 8.- P. 3250-3254. doi: 10.1063/1.351444.2.
  2. Fontana, M. Optical damage resistance in undoped LiNbO3 crystals / M. Fontana, K. Chah, M. Aillerie et al. // Optical Materials. - 2001. - V. 16. - I. 1-2. - P. 111-117. doi: 10.1016/S0925-3467(00)00066-5.
  3. Bryan, D.A. Increased optical damage resistance in lithium niobate / D.A. Bryan, R. Gerson, H.E. Tomaschke // Applied Physics Letters. - 1984. - V. 44. - I. 9. - P. 847-849. doi: 10.1063/1.94946.
  4. Volk, T.R. Optical-damage-resistant Impurities in Lithium Niobate / T.R. Volk, N.M. Rubinina, M. Woehlecke // Journal of the Optical Society of America B: Optical Physics. - 1994. - V. 11. - I. 9. - P. 1681-1687. doi: 10.1364/JOSAB.11.001681.
  5. Abdi, F. Coexistence of Li and Nb vacancies in the defect structure of pure LiNbO3 and its relationship to optical properties / F. Abdi, M.D. Fontana, M. Aillerie et al. // The Journal of Applied Physics A. - 2006.- V. 83. - I. 3. - P. 427-434. doi: 10.1007/S00339-006-3565-5.
  6. Volk, T.R. Optical-damage-resistant LiNbO3:Zn crystal / T.R. Volk, V.I. Pryalkin, N.M. Rubinina // Optics Letters. - 1990. - V. 15. - I. 18. - P. 996-998. doi: 10.1364/OL.15.000996.
  7. Aillerie, M. Photorefractive damage in congruent LiNbO3. Part I. Zinc doped lithium niobate crystals / M. Aillerie, P. Bourson, M. Mostefa et al. // The Journal of Physics: Conference Series. NAMES10: "New achievements in materials and environmental sciences", 26-29 October 2010, Nancy, France. - 2013. - V. 416.- Art. № 012001. - 10 p. DOI: 1742-6596/416/1/012001.
  8. Sidorov, N.V. Synthesis of homogeneous doping with zinc charge of lithium niobate and comparative study of LiNbO3:Zn crystals of different genesis / N.V. Sidorov, L.A. Bobreva, S.M. Masloboeva et al. // Inorganic Materials: Applied Research. - 2019. - V. 10. - I. 5. - P. 1196-1203. doi: 10.1134/S2075113319050307.
  9. Палатников, М.Н. Фундаментальные аспекты технологии сильно легированных кристаллов ниобата лития / М.Н. Палатников, Н.В. Сидоров, О.В. Макарова, И.В. Бирюкова. - Апатиты: КНЦ РАН, 2017.-241 с.
  10. Palatnikov, M.N. The search of homogeneity of LiNbO3 crystals grown of charge with different genesis / M.N. Palatnikov, I.V. Biryukova, S.M. Masloboeva et al. // The Journal of Crystal Growth. - 2014. - V. 386.- P. 113-118. doi: 10.1016/j.jcrysgro.2013.09.038.
  11. Zhao, L. ZnO-doped LiNbO3 single crystals studied by X-ray and density measurements / L. Zhao, X. Wang, B. Wang et al. // Applied Physics B. - 2004. - V. 78. - I. 6. - P. 769-774. doi: 10.1007/s00340-004-1503-9.
  12. Zhang, Y. Growth and properties of Zn doped lithium niobate crystal / Y. Zhang, Y.H. Xu, M.H. Li et al. // The Journal of Crystal Growth. - 2001. - V. 233. - I. 3. - P. 537-540. doi: 10.1016/S0022-0248(01)01614-1.
  13. Chernaya, T.S. Threshold concentrations in zinc-doped lithium niobate crystals and their structural conditionality / T.S. Chernaya, T.R. Volk, I.A. Verin et al. // Crystallography Reports. - 2008. - V. 53. - I. 4.- P. 573-578. doi: 10.1134/S106377450804007X.
  14. Sidorov, N.V. Photorefractive properties of congruent lithium niobate crystals doped with zinc / N.V. Sidorov, M.N. Palatnikov, N.A. Teplyakova et al. // Inorganic Materials: Applied Research. - 2016. - V. 7. - I. 2. - P. 170-176. doi: 10.1134/S2075113316020209.
  15. Sidorov, N.V. Complex investigations of structural and optical homogeneities of low-photorefractivity lithium niobate crystals by the conoscopy and photoinduced and raman light scattering methods / N.V. Sidorov, O.Yu. Pikoul, A.A. Kruk et al. // Optics and spectroscopy. - 2015. - V. 118. - I. 2. - P. 259-268. doi: 10.1134/S0030400X15020174.
  16. Palatnikov, M.N. Investigation of structural and optical homogeneity of LiNbO3:ZnO crystals of different genesis / M.N. Palatnikov, N.V. Sidorov, A.V. Kadetova et al. // Inorganic Materials: Applied Research.- 2020. - V. 11. - I. 2. - P. 320-329. doi: 10.1134/S207511332002029X.
  17. Masloboeva, S.M. Growth and characterization of a boron-doped lithium niobate single crystal / S.M. Masloboeva, I.N. Efremov, I.V. Biryukova et al. Inorganic Materials. - 2020. - V. 56. - I. 11. - P. 1147-1152. doi: 10.1134/S0020168520110072.
  18. Сидоров, Н.В. Лазерная коноскопия и фотоиндуцированное рассеяние света в исследованиях свойств нелинейно-оптического кристалла ниобата лития / Н.В. Сидоров, О.Ю. Пикуль, Н.А. Теплякова, М.Н. Палатников. - Москва: РАН, 2019. - 350 с.
  19. Biryukova I.V. Preparation and characterization of lithium niobate single crystals doped with 4.02-5.38 mol % Zn / I.V. Biryukova, S.M. Masloboeva, I.N. Efremov et al. // Inorganic Materials. - 2023. - V. 59.- I. 2. - P. 169-175. doi: 10.1134/S0020168523020048.

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