Investigation of the effect of titanium and zirconium oxides on the strength characteristics of nanoscale hydroxyapatite

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Abstract

The article discusses the possibility of dispersion strengthening of nanostructured hydroxyapatite synthesized by precipitation from solution introducing reinforcing additives of non-stoichiometric titanium oxide and zirconium dioxide. The reinforced composite material: hydroxyapatite - non-stoichiometric titanium oxide - zirconium dioxide was obtained by mechanochemical synthesis of hydroxyapatite with doping components followed by annealing at 1000°C. The initial components and synthesized samples were certified using modern physicochemical methods of analysis: X-ray phase analysis, differential thermal analysis, scanning electron microscopy, surface area and porosity analysis, dispersion analysis. The influence of the qualitative and quantitative composition of the composite on the sintering processes and strength characteristics of the studied samples in a wide temperature range of 25-1200°C is shown. It has been experimentally established that the most promising system for developing biocomposites based on it is hydroxyapatite - 15% non-stoichiometric titanium oxide - 5% zirconium dioxide. Composite materials of this composition have a dense, uniform, strong structure with a high degree of crystallinity and a developed surface. They seem to be promising materials for further research with the aim of introducing it into medical practice.

About the authors

Kirill I. Sabanin

Ural Federal University named after the first President of Russia B.N. Yeltsin

4th year student, Department of Experimental Physics

Vladimir M. Skachkov

Institute of Solid State Chemistry of the Ural Branch of RAS

Email: skachkov@ihim.uran.ru
Ph. D., Senior Researcher, Laboratory of Heterogeneous Processes Chemistry

Irina S. Medyankina

Institute of Solid State Chemistry of the Ural Branch of RAS

Researcher, Laboratory of Promising and Functional Materials for Chemical Current Source

Ekaterina A. Bogdanova

Institute of Solid State Chemistry of the Ural Branch of RAS; JSC «Giredmet»

Ph. D., Senior Researcher, Laboratory of Heterogeneous Processes Chemistry, Institute of Solid State Chemistry of the Ural Branch of RAS; Leading Researcher, Laboratory of Electrochemical Devices for Hydrogen Energy, JSC Giredmet

Nail A. Sabirzyanov

Institute of Solid State Chemistry of the Ural Branch of RAS

Dr. Sc., Chief Researcher, Head of the Laboratory of Heterogeneous Processes Chemistry

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