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Volume 8, Nº 6 (2017)

Structural–Technological Strenghts and Working Capacity of Materials

On calculation of the contour size of the J-integral for assessment of the structural integrity of the VVER reactor pressure vessels under emergency core cooling

Margolin B., Kostylev V., Fomenko V., Akbashev I., Matkovsky V.

Resumo

The procedure for calculating the J-integral for assessment of the lifetime of a reactor pressure vessel was developed according to the brittle fracture criterion under emergency core cooling conditions. An approach to the choice of the size of the integration contour was formulated for an adequate assessment of the brittle fracture resistance.

Inorganic Materials: Applied Research. 2017;8(6):914-926
pages 914-926 views

Metal Sciences. Metallurgy

Controlling behavior of δ-ferrite in nitrogen-containing chromium–nickel–manganese steels

Kazakov A., Oryshchenko A., Fomina O., Zhitenev A., Vikhareva T.

Resumo

This article discusses the behavior of δ-ferrite upon crystallization, solidification, and subsequent cooling of solid nitrogen-containing stainless steel of various compositions on the basis of thermodynamic simulation. The results are confirmed experimentally and can be applied for selection of the steel composition as well as its production at all stages, including hot plastic working and welding, where δ-ferrite can be useful provided that its content is controlled. These results can be applied also for selection of temperature modes of austenitization aiming at the most complete dissolution of δ-ferrite in the final metal.

Inorganic Materials: Applied Research. 2017;8(6):817-826
pages 817-826 views

Structure and properties of new wear-resistant steels for agricultural machine building

Ryabov V., Kniaziuk T., Mikhailov M., Motovilina G., Khlusova E.

Resumo

The phase transformations and the changes in the structure and mechanical properties of highstrength steel are studied under the common treatment operations (hot rolling, stamping, and heat treatment). On the basis of the results of research, new competitive wear-resistant steels with the yield strengths of 1200, 1500, and 1700 MPa are developed for the agricultural machine building industry.

Inorganic Materials: Applied Research. 2017;8(6):827-836
pages 827-836 views

Development of the high-strength titanium pseudo-β-alloy and semifinished products thereof

Kablov E., Nochovnaya N., Gribkov Y., Shiriaev A.

Resumo

High-strength titanium pseudo-β-alloy (VT47) alloyed with rare earth metals intended for the geometrically complex plate structures of aircraft was developed. A combination of mechanical and technological properties for the VT47 alloy after its thermal treatment in different modes was shown. The further possible development of new materials with regulated β-structure was shown.

Inorganic Materials: Applied Research. 2017;8(6):837-842
pages 837-842 views

Optimization of heat treatment hardening modes for semifinished products of Ti-5553 pseudo-β-alloy for marine applications

Kudryavtsev A., Chudakov E., Kulik V., Tretyakova N., Berestov A., Fedorov S.

Resumo

The paper studies the structure and mechanical properties of plate metal made of Ti-5553 pseudo-β-alloy after hardening heat treatment in various modes. The possibility of obtaining the necessary set of physical and mechanical properties for deformed semifinished products of large thickness used in shipbuilding by selecting the optimal mode of hardening heat treatment is shown.

Inorganic Materials: Applied Research. 2017;8(6):843-847
pages 843-847 views

Study of nanostructure of experimental Ti–5Al–4V–2Zr alloy

Rogozhkin S., Schastlivaya I., Leonov V., Nikitin A., Orlov N., Kozodaev M., Vasiliev A., Orekhov A.

Resumo

The microstructure and chemical composition of phases and inclusions in Ti–5Al–4V–2Zr alloys are studied in the initial state, after irradiation by titanium ions to radiation damage dose of ~1 dpa at 260°C, and after thermal aging at 450°C for 1000 h. Microstructural studies are carried out using scanning electron microscopy and atom probe tomography. Phase analysis is performed using energy dispersive X-ray spectroscopy. Chemical analysis of grains of the matrix phase and β-phase is presented. Spatial distribution of chemical elements in α- and β-phase lamellae is analyzed by atom probe tomography. Formation of nanosized vanadium pre-precipitates in the α-phase is observed in irradiated material.

Inorganic Materials: Applied Research. 2017;8(6):848-860
pages 848-860 views

Functional Materials

Structure and properties of the bronze-based functional coating obtained by gas-dynamic and microplasma spraying

Bobkova T., Chernysh A., Masailo A., Deev A., Klimov V., Yurkov M.

Resumo

Taken as a basis, BrAZhNMts 8-1.5-5-1.5 bronze powder was used to investigate the possibilities of applying functional-gradient coatings by gas-dynamic and microplasma spraying. It was experimentally established, that the oxide film on the surface of bronze particles hinders the formation of the coating by gasdynamic spraying. Two methods for the oxide film destruction were suggested: the first one was utilization of alumina in the spraying process, and the second one was manufacturing composite bronze-based powder in a vibrating mill. The influence of ceramic particles on the bronze coating hardness was investigated. The paper analyzes the prospects of using such coatings for the protection of important parts of marine equipment.

Inorganic Materials: Applied Research. 2017;8(6):861-869
pages 861-869 views

Biotechnological studies at the nanocenter of the Central Research Institute of Structural Materials Prometey

Gorynin I., Oryshchenko A., Farmakovsky B., Vasileva O., Vasilev A., Vinogradova T., Eshmemeteva E., Mukhamedzianova L., Samodelkin E., Kuznetcov P.

Resumo

The paper presents results of experimental biotechnological research that has been carried out at the Nanotechnological Center of the Central Research Institute of Structural Materials Prometey. This includes development of gradient functional coatings (bactericidal, anticorrosion, catalytically active) and defense systems for biological objects against negative influence of magnetic and electromagnetic radiation; high-speed shock wave treatment of medicines, phytomaterials, and alimentary, fodder, and medical products; and laser technologies for creating hybrid biomimetic compositions.

Inorganic Materials: Applied Research. 2017;8(6):870-880
pages 870-880 views

Polymer Composite Materials

New heat-resistant electrical insulating fiberglass

Bakhareva V., Sargsyan A.

Resumo

The paper presents the results of comparative tests for new heat-resistant electrical insulating polymer composite materials based on glass tissue and various polymeric binders and designed to operate at temperatures up to 280°C. Thermosetting (epoxy, organosilicon, and polycyanurate) and thermoplastic (polyphenylene sulfide) binders are investigated.

Inorganic Materials: Applied Research. 2017;8(6):881-885
pages 881-885 views

Welding and Related Processes. Welding Materials and Technologies

Effect of welding thermal cycle on structural and phase weld metal transformations for heat-resistant Cr–Mo–V steels

Timofeev M., Karzov G., Galyatkin S., Mikhaleva E.

Resumo

Results are presented for dilatometric and metallographic investigations and determination of microhardness for weld metal made of the materials for the automatic welding of VVER reactor vessels and oil hydrocracking reactor vessels. It is found that small differences in the content of alloying elements, such as nickel, chromium, molybdenum, and vanadium, cause differences in the structure of the weld metal before heat treatment.

Inorganic Materials: Applied Research. 2017;8(6):886-891
pages 886-891 views

Activated soldering of dissimilar materials with amorphous solders

Gorynin I., Farmakovsky B., Vasiliev A., Vinogradova T., Samodelkin E.

Resumo

The features of soldering of dissimilar materials using amorphous solders (for example, steel–titanium pair) have been investigated. To reduce the soldering temperature below the phase transformation temperature and to retain the advantages of the solution-diffusion junction, compositions for amorphous alloy solders have been developed representing a powder mixture of amorphous solder based on titanium VPr-16 with low-melting solders based on gallium and indium. The efficiency of activated soldering has been tested from the standpoint of mechanical strength using cylindrical butt-soldered samples, the elements of a steel–titanium tube board, and some specific complex structures of heat exchange systems, etc. On the basis of the X-ray spectral analysis of soldered joints using a Camebax micro unit, it is established that the diffusion zone of a soldered joint is about 100 μm. The solder is completely consumed during the formation of the diffusion layer, the independent phase is not retained, which provides high strength properties of the soldered junction. The developed approach to the creation of hard-packed soldered structures from dissimilar materials is basic and has been successfully implemented for a number of other compositions, including the soldering of aluminum, steel, and NiCr; copper and a quasicrystalline Al–Cu–Fe alloy; and titanium and ruthenium. Examples of successful practical implementation of the results are presented.

Inorganic Materials: Applied Research. 2017;8(6):892-898
pages 892-898 views

Corrosion and Protection of Metals

New ice-resistant platinum-niobium anodes for cathodic protection systems against erosion-corrosion damage of icebreakers and offshore structures

Stavitsky O., Kuzmin Y., Troshchenko V.

Resumo

The paper considers new generation platinum-niobium anodes developed on the basis of the 15-year experience of AKK-M-4 anodes operating as a part of a cathodic protection system for the nuclearpowered icebreaker 50 Let Pobedy, which can provide protection against erosion-corrosion damage of modern icebreakers and undocked ice-resistant offshore structures without repair and replacement for up to 25 years or more. Updated ice-resistant anodes such as AKL-2MU and AKL-3MU have been developed.

Inorganic Materials: Applied Research. 2017;8(6):899-905
pages 899-905 views

The influence of ruthenium on structure, corrosion and mechanical properties, and fatigue characteristics of titanium α-alloys in corrosive environment

Malinkina Y., Chudakov E., Leonov V.

Resumo

This article discusses test results of corrosion mechanical properties and fatigue properties of deformed semifinished items (forgings and pipes) made of titanium alloys PT-7M and PT-7M with addition of ruthenium. The main mechanical properties of titanium alloys, the structure, and the ruthenium distribution in the structure are determined. Results of static three-point bending tests of specimens with crack are discussed for determination of corrosion mechanical strength and cyclic fatigue strength of forgings and pipes of these alloys in a corrosive medium.

Inorganic Materials: Applied Research. 2017;8(6):906-913
pages 906-913 views

Radiation Materials Science

Comparative studies of brittle fracture mechanism for standard and reconstructed CT specimens made of VVER-1000 RPV materials

Erak A., Kuleshova E., Bubiakin S., Bandura A., Zhurko D.

Resumo

Before 2002, SE(B) specimens were included in surveillance specimen sets for operating VVER-1000 reactors. The transition from SE(B) specimens to CT specimens in the fracture toughness tests is caused by the necessity to reduce the scatter and the conservativeness of results caused by the scale increase and the loading scheme. To make such a transition possible, SE(B) specimens were reconstructed into CT specimens. The comparative fractographic analysis of standard and reconstructed CT specimens after the fracture toughness tests shows that the crack initiation in both types starts from the “origin.” The types of “origins” and their ratios do not change, and the test results and the fractographic analysis data for standard and reconstructed CT specimens are described by one analytical dependence CTOD(CID) for each material and state.

Inorganic Materials: Applied Research. 2017;8(6):927-935
pages 927-935 views

Prediction of radiation embrittlement of WWER-1000 reactor vessel materials considering the influence of alloying elements and high content of copper

Margolin B., Yurchenko E.

Resumo

Basing on the analysis of the radiation embrittlement of RPV materials, the paper proposes a model and dependencies for description of WWER-1000 vessel material embrittlement with copper content above 0.10%. Standard dose-time trend curves have been modernized. The dose-time trend curves have been modernized.

Inorganic Materials: Applied Research. 2017;8(6):936-943
pages 936-943 views

Investigation of radiation resistance and structural stability of titanium α-and pseudo-α-alloys

Schastlivaya I., Leonov V., Khanzhin A., Obukhov A., Makarov O., Kudrin Y.

Resumo

The radiation resistance of advanced Ti–5Al–4V–2Zr, Ti–5Al–2Mo–2Zr, and Ti–4Al–Mo–20Zr titanium alloys after neutron irradiation damaging dose of 0.29 dpa at irradiation temperature of 260°C was studied. The results of mechanical and microstructural tests of specimens carried out by transmission electron microscopy are presented; the distribution profiles of the alloying elements obtained by the energydispersive X-ray spectroscopy were studied.

Inorganic Materials: Applied Research. 2017;8(6):944-950
pages 944-950 views

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