Curing of ED-20 Epoxy Resin with Diesterdisulfoanhydride of 2-Hydroxypropyl Saccharin-6-Carboxylic Acid
- Authors: Aslanova E.T.1, Aslanov T.A.1, Mamedov B.A.1, Mamedova A.A.1
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Affiliations:
- Institute of Polymer Materials, Azerbaijan National Academy of Sciences
- Issue: Vol 10, No 2 (2019)
- Pages: 391-395
- Section: General Purpose Materials
- URL: https://journals.rcsi.science/2075-1133/article/view/207868
- DOI: https://doi.org/10.1134/S2075113319020023
- ID: 207868
Cite item
Abstract
Diesterdisulfoanhydride of 2-hydroxypropyl saccharin-6-carboxylic acid has been obtained by interaction of monoanhydride of sulfoimide of saccharin-6-carboxylyc acid with 1,3-diacetine. The composition and structure of the synthesized compound have been confirmed by the elemental analysis and IR spectroscopy data. The obtained product has been used as a curing agent and a plasticizer for industrial ED-20 epoxy resin. It has been established that diesterdisulfoanhydride of 2-hydroxypropyl saccharin-6-carboxylic acid is an effective curing agent and plasticizer for ED-20 epoxy resin. The composition curing process has been studied by differential thermal analysis using a Paulik-Paulik-Erdey derivatograph. On the basis of the data obtained, it has been revealed that the synthesized diesterdisulfoanhydride combines well with ED-20 epoxy resin but cures it in a severe temperature mode. It has been shown that, by using nadic methyl anhydride as a cocuring agent and an accelerator, the curing temperature range of the composition is shifted to a lower temperature zone. The compositions and structures of initial epoxy resin and cured products have also been determined by elemental analysis and IR spectroscopy.
Keywords
About the authors
E. T. Aslanova
Institute of Polymer Materials, Azerbaijan National Academy of Sciences
Author for correspondence.
Email: ipoma@science.az
Azerbaijan, Sumgait, AZ5004
T. A. Aslanov
Institute of Polymer Materials, Azerbaijan National Academy of Sciences
Author for correspondence.
Email: ipoma@science.az
Azerbaijan, Sumgait, AZ5004
B. A. Mamedov
Institute of Polymer Materials, Azerbaijan National Academy of Sciences
Author for correspondence.
Email: bazisaley@mail.ru
Azerbaijan, Sumgait, AZ5004
A. A. Mamedova
Institute of Polymer Materials, Azerbaijan National Academy of Sciences
Author for correspondence.
Email: afmasum@mail.ru
Azerbaijan, Sumgait, AZ5004