Formation and Properties of Electron- and Ion-Conducting Layers of N-Substituted PVC Derivatives Grafted onto Active Carbon


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A systematization is presented of studies of carbon sorbent functionalization based on chemical modification of the active carbon surface by covalent grafting of macromolecular N-substituted cyclic amines. Thus, porous electron-conducting and luminescent layers grafted onto supports are obtained. The layers can sorb organic compounds. After sorption of acids, hydroxides, and metal salts, the layers become electron- and ion-conducting. Here, hydrogen is formed as in cathodically polarized electrochemical bridges and oxygen is formed as in anodically polarized electrochemical bridges. Principles of layer formation are considered on the surface of the material of cellulose fibers and asbestos cloth, as well as nickel filaments. Specific features of such functionalized sorbents are shown.

作者简介

I. Bardyshev

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

编辑信件的主要联系方式.
Email: bardyshev@phyche.ac.ru
俄罗斯联邦, Moscow, 119071

I. Polyakova

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: bardyshev@phyche.ac.ru
俄罗斯联邦, Moscow, 119071

A. Gorbunov

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: bardyshev@phyche.ac.ru
俄罗斯联邦, Moscow, 119071

V. Titova

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: bardyshev@phyche.ac.ru
俄罗斯联邦, Moscow, 119071

A. Yavich

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: bardyshev@phyche.ac.ru
俄罗斯联邦, Moscow, 119071

A. Tsivadze

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: bardyshev@phyche.ac.ru
俄罗斯联邦, Moscow, 119071

A. Fridman

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: bardyshev@phyche.ac.ru
俄罗斯联邦, Moscow, 119071

A. Averin

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: bardyshev@phyche.ac.ru
俄罗斯联邦, Moscow, 119071

M. Shabanov

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: bardyshev@phyche.ac.ru
俄罗斯联邦, Moscow, 119071

E. Morozova

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: bardyshev@phyche.ac.ru
俄罗斯联邦, Moscow, 119071

G. Petukhova

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: bardyshev@phyche.ac.ru
俄罗斯联邦, Moscow, 119071

A. Novikov

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: bardyshev@phyche.ac.ru
俄罗斯联邦, Moscow, 119071

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