Formation and Properties of Electron- and Ion-Conducting Layers of N-Substituted PVC Derivatives Grafted onto Active Carbon
- Авторлар: Bardyshev I.I.1, Polyakova I.Y.1, Gorbunov A.M.1, Titova V.N.1, Yavich A.A.1, Tsivadze A.Y.1, Fridman A.Y.1, Averin A.A.1, Shabanov M.P.1, Morozova E.M.1, Petukhova G.A.1, Novikov A.K.1
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Мекемелер:
- Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
- Шығарылым: Том 55, № 6 (2019)
- Беттер: 1071-1079
- Бөлім: Physicochemical Processes at the Interfaces
- URL: https://journals.rcsi.science/2070-2051/article/view/205563
- DOI: https://doi.org/10.1134/S2070205119050265
- ID: 205563
Дәйексөз келтіру
Аннотация
A systematization is presented of studies of carbon sorbent functionalization based on chemical modification of the active carbon surface by covalent grafting of macromolecular N-substituted cyclic amines. Thus, porous electron-conducting and luminescent layers grafted onto supports are obtained. The layers can sorb organic compounds. After sorption of acids, hydroxides, and metal salts, the layers become electron- and ion-conducting. Here, hydrogen is formed as in cathodically polarized electrochemical bridges and oxygen is formed as in anodically polarized electrochemical bridges. Principles of layer formation are considered on the surface of the material of cellulose fibers and asbestos cloth, as well as nickel filaments. Specific features of such functionalized sorbents are shown.
Негізгі сөздер
Авторлар туралы
I. Bardyshev
Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Хат алмасуға жауапты Автор.
Email: bardyshev@phyche.ac.ru
Ресей, Moscow, 119071
I. Polyakova
Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Email: bardyshev@phyche.ac.ru
Ресей, Moscow, 119071
A. Gorbunov
Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Email: bardyshev@phyche.ac.ru
Ресей, Moscow, 119071
V. Titova
Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Email: bardyshev@phyche.ac.ru
Ресей, Moscow, 119071
A. Yavich
Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Email: bardyshev@phyche.ac.ru
Ресей, Moscow, 119071
A. Tsivadze
Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Email: bardyshev@phyche.ac.ru
Ресей, Moscow, 119071
A. Fridman
Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Email: bardyshev@phyche.ac.ru
Ресей, Moscow, 119071
A. Averin
Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Email: bardyshev@phyche.ac.ru
Ресей, Moscow, 119071
M. Shabanov
Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Email: bardyshev@phyche.ac.ru
Ресей, Moscow, 119071
E. Morozova
Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Email: bardyshev@phyche.ac.ru
Ресей, Moscow, 119071
G. Petukhova
Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Email: bardyshev@phyche.ac.ru
Ресей, Moscow, 119071
A. Novikov
Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Email: bardyshev@phyche.ac.ru
Ресей, Moscow, 119071
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