Thermally Stimulated Evolution of the Surface of Ni- and Cu-Containing Plasma-Electrolytic Oxide Coatings on Titanium
- Авторы: Rudnev V.S.1,2, Lukiyanchuk I.V.1, Vasilyeva M.S.1,2, Zvereva A.A.1
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Учреждения:
- Institute of Chemistry, Far East Branch, Russian Academy of Sciences
- Far Eastern Federal University
- Выпуск: Том 55, № 4 (2019)
- Страницы: 719-728
- Раздел: New Substances, Materials, and Coatings
- URL: https://journals.rcsi.science/2070-2051/article/view/205372
- DOI: https://doi.org/10.1134/S2070205119040178
- ID: 205372
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Аннотация
The effect of the temperature of annealing in air on the surface architecture and composition of oxide layers has been studied. Copper-enriched nanosized crystals of triangular shape are present on the surface at the annealing temperatures of 500–700°С. Rectangular nano- and microcrystals of a possible composition of NiWO4 are formed on the surface after annealing at 750–850°С. Nanowhisker brushes, similar in composition to nickel titanates, cover the surface after annealing at 900–950°С. Transformation of the surface architecture and composition on the micro- and nanolevels correlates to the coatings’ activity in the catalysis of the reaction of oxidation of CO to CO2.
Об авторах
V. Rudnev
Institute of Chemistry, Far East Branch, Russian Academy of Sciences; Far Eastern Federal University
Автор, ответственный за переписку.
Email: rudnevvs@ich.dvo.ru
Россия, Vladivostok, 690022; Vladivostok, 690091
I. Lukiyanchuk
Institute of Chemistry, Far East Branch, Russian Academy of Sciences
Email: rudnevvs@ich.dvo.ru
Россия, Vladivostok, 690022
M. Vasilyeva
Institute of Chemistry, Far East Branch, Russian Academy of Sciences; Far Eastern Federal University
Email: rudnevvs@ich.dvo.ru
Россия, Vladivostok, 690022; Vladivostok, 690091
A. Zvereva
Institute of Chemistry, Far East Branch, Russian Academy of Sciences
Email: rudnevvs@ich.dvo.ru
Россия, Vladivostok, 690022
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