Corrosion of AD31 (AA6063) Alloy in Chloride-Containing Solutions


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Corrosion of AD31 (AA6063) alloy in neutral 0.05 M NaCl solutions is investigated via scanningprobe microscopy, linear-sweep voltammetry, and electrochemical-impedance spectroscopy. Al−Fe−Si−Mg intermetallic particles are determined to prevail in the structure of alloy and act as local cathodes. Intermodulation electrostatic-force-microscopy imaging shows that their Volta potential differs by 570 mV from that of the host aluminum matrix, making the alloy prone to localized corrosion. We show that the corrosion of alloy in the studied electrolyte mainly develops locally and results in pitting, with charge transfer being the limiting stage of the process. A mechanism of corrosion of the AD31 (AA6063) alloy in neutral chloride-containing solutions is proposed.

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D. Kharitonov

Department of Chemistry, Technology of Electrochemical Production and Electronic Engineering Materials; Surface and Corrosion Science Division

编辑信件的主要联系方式.
Email: kharitonov@belstu.by
白俄罗斯, Minsk, 220006; Drottning Kristinas väg 51, Stockholm, SE-100 44

I. Dobryden’

Surface and Corrosion Science Division

Email: kharitonov@belstu.by
瑞典, Drottning Kristinas väg 51, Stockholm, SE-100 44

B. Sefer

Division of Materials Science

Email: kharitonov@belstu.by
瑞典, Luleå, SE-97187

I. Zharskii

Department of Chemistry, Technology of Electrochemical Production and Electronic Engineering Materials

Email: kharitonov@belstu.by
白俄罗斯, Minsk, 220006

P. Claesson

Surface and Corrosion Science Division; Division of Chemistry, Materials, and Surfaces

Email: kharitonov@belstu.by
瑞典, Drottning Kristinas väg 51, Stockholm, SE-100 44; Stockholm, SE-114 86

I. Kurilo

Department of Physical, Colloid and Analytical Chemistry

Email: kharitonov@belstu.by
白俄罗斯, Minsk, 220006

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