Corrosion and Physical-Mechanical Properties of Cr–P–W Alloy Obtained by Electrodeposition from Water–Dimethylformamide Electrolytes


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Abstract

Cr–P–W protective coatings are obtained by electrodeposition from water–dimethylformamide solutions based on chromium(III) chloride, with the addition of sodium phosphinate and sodium tungstate. The resulting alloys contained up to 8 wt % of phosphorus and 1.5 wt % of tungsten, as well as some carbon. The resulting coatings are characterized by satisfactory corrosion resistance in corrosive environments containing chloride ions. The number of through pores in the coatings became negligible with a coating thickness more than 15 μm, providing sufficient protective ability of the developed coatings.

About the authors

A. V. Telezhkina

Mendeleev University of Chemical Technology

Email: Madjerre@mail.ru
Russian Federation, Moscow, 125047

V. V. Kuznetsov

Mendeleev University of Chemical Technology; Frumkin Institute of Physical Chemistry and Electrochemistry

Author for correspondence.
Email: Vitkuzn1@mail.ru
Russian Federation, Moscow, 125047; Moscow, 119071

E. A. Filatova

Mendeleev University of Chemical Technology

Email: Madjerre@mail.ru
Russian Federation, Moscow, 125047

N. E. Nekrasova

Mendeleev University of Chemical Technology

Author for correspondence.
Email: Madjerre@mail.ru
Russian Federation, Moscow, 125047

V. V. Zhulikov

National Research Nuclear University MEPhI

Email: Madjerre@mail.ru
Russian Federation, Moscow, 115409

V. A. Kolesnikov

Mendeleev University of Chemical Technology

Email: Madjerre@mail.ru
Russian Federation, Moscow, 125047

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