Variant of a Solution of an Inverse Problem in the Linear Dynamics of Adsorption


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Abstract

The form of elution curves in the linear frontal dynamics of adsorption is studied based on the exact solution of a direct problem. It is determined that there is an intersection of the elution curves calculated in dimensionless coordinates under different values of the effectiveness of the adsorbent layer at a relative concentration corresponding to about 0.68. The determined principle allows us to develop an algorithm to determine the adsorption and kinetic constants for the initial values of effectiveness. The solution of an inverse problem of the linear dynamics of adsorption on the example of the model elution curve is demonstrated.

About the authors

A. V. Larin

Frumkin Institute of Physical Chemistry and Electrochemistry

Author for correspondence.
Email: larin@phyche.ac.ru
Russian Federation, Moscow, 119071

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