Heat and Recrystallization Processes in Polyethylene–Cyanuric Acid Mixtures after Plastic Deformation under High Pressure


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Abstract

LDPE and SMPE mixtures with cyanuric acid (40–90 wt %) underwent plastic deformation under 0.5–3.0 GPa and were analyzed with DSC. We found that cold crystallization proceeds during heating the deformed mixtures in LDPE and the enthalpy of melting decreases. Ultrafine crystallites are formed in the mixtures with SMPE, and the enthalpy of melting increases by 1.8 times.

About the authors

V. A. Zhorin

Semenov Institute of Chemical Physics, Russian Academy of Sciences

Author for correspondence.
Email: vzhorin@mail.ru
Russian Federation, Moscow, 119991

M. R. Kiselev

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: kisselev@phych.ac.ru
Russian Federation, Moscow, 117915

V. A. Kotenev

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Author for correspondence.
Email: kisselev@phych.ac.ru
Russian Federation, Moscow, 117915

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