Hydroxyapatite Coating on Fluorine-treated Magnesium Alloy by Hydrothermal Method and Its Electrochemical Corrosion Behaviour in Hank’s Solution


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Abstract

In order to improve the corrosion resistance and biocompatibility of magnesium alloys, hydroxyapatite (HA) coating with an outer chrysanthemum-like crystals layer and an inner needle-like crystals layer was successfully prepared on fluorine-treated AZ31 magnesium alloy by hydrothermal treatment. The needle-like crystals was about 1 μm long and grew almost vertically from fluoride conversion film. The inner layer arranged orderly and compactly, while the outer layer was thick but loose. The HA coating increased the open circuit potential, decreased the corrosion current density and improved the Rf and Rct of fluoride coated sample, indicating that the HA coating can delay the degradation of fluoride conversion film and postpone the corrosion of AZ31 alloy in Hank’s solution.

About the authors

Zhang Chunyan

School of Materials Science & Engineering, Chongqing University of Technology; Chongqing Municipal Engineering Research Center of Institutions of Higher Education
for Special Welding Materials and Technology

Author for correspondence.
Email: zhangchunyan@cqut.edu.cn
China, Chongqing, 400054; Chongqing, 400054

Ma Yanlong

School of Materials Science & Engineering, Chongqing University of Technology; Chongqing Municipal Engineering Research Center of Institutions of Higher Education
for Special Welding Materials and Technology

Email: zhangchunyan@cqut.edu.cn
China, Chongqing, 400054; Chongqing, 400054

Liu Chenglong

School of Materials Science & Engineering, Chongqing University of Technology

Email: zhangchunyan@cqut.edu.cn
China, Chongqing, 400054

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