Email this article The First Example of Electron Phototransfer with the Participation of Two-Decker Lanthanide Phthalocyaninate
- Authors: Gromova G.A.1, Lobanov A.V.2,3, Gorbunova Y.G.4,5, Tsivadze A.Y.4,5
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Affiliations:
- Moscow Technological University
- Semenov Institute of Chemical Physics
- Plekhanov Russian University of Economics
- Frumkin Institute of Physical Chemistry and Electrochemistry
- Kurnakov Institute of General and Inorganic Chemistry
- Issue: Vol 54, No 2 (2018)
- Pages: 170-173
- Section: Molecular and Supramolecular Structures at the Interfaces
- URL: https://journals.rcsi.science/2070-2051/article/view/203851
- DOI: https://doi.org/10.1134/S2070205118020065
- ID: 203851
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Abstract
The photochemical activity of the anionic form of two-decker ytterbium and lutetium pthalocyaninates (LnPc2, Ln = Yb, Lu) is observed in the process of electron transfer to 2-methyl-1,4-naphthoquinone (MNQ). Under illumination of solutions of LnPc2 (1 × 10–5 mol/L) and MNQ (5 × 10–5 mol/L) in dimethyl formamide by light with wavelength λph > 630 nm, the anionic form of the two-decker phthalocyaninate [(Pc2–)Ln3+(Pc2–)]– passes into the neutral monoradical form [(Pc2–)Ln3+(Pc–)]0•. The photochemical redox process is accompanied by accumulation of the reduced form of MNQ. The observed effect is the first example of electron phototransfer with the participation of two-decker lanthanide phthalocyaninates.
About the authors
G. A. Gromova
Moscow Technological University
Email: avlobanov@mail.ru
Russian Federation, Moscow, 119571
A. V. Lobanov
Semenov Institute of Chemical Physics; Plekhanov Russian University of Economics
Author for correspondence.
Email: avlobanov@mail.ru
Russian Federation, Moscow, 119991; Moscow, 117997
Yu. G. Gorbunova
Frumkin Institute of Physical Chemistry and Electrochemistry; Kurnakov Institute of General and Inorganic Chemistry
Email: avlobanov@mail.ru
Russian Federation, Moscow, 119071; Moscow, 119991
A. Yu. Tsivadze
Frumkin Institute of Physical Chemistry and Electrochemistry; Kurnakov Institute of General and Inorganic Chemistry
Email: avlobanov@mail.ru
Russian Federation, Moscow, 119071; Moscow, 119991
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