The Photoelectrochemical Activity of Titanium Dioxide Nanosized Films in the Visible Spectral Region


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Abstract

From solutions of organic precursors, nanosized films of titanium dioxide with photoelectrochemical activity in the visible region are obtained. A possibility of photoelectrochemical oxidation of a number of organic compounds under illumination with monochromatic light at a wavelength of 464 nm is demonstrated, which may be due to a decrease in the n-TiO2 band-gap energy to 2.7 eV.

About the authors

V. A. Grinberg

Frumkin Institute of Physical Chemistry and Electrochemistry

Author for correspondence.
Email: vgrinberg@phyche.ac.ru
Russian Federation, Moscow, 119071

V. V. Emets

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: vgrinberg@phyche.ac.ru
Russian Federation, Moscow, 119071

N. A. Maiorova

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: vgrinberg@phyche.ac.ru
Russian Federation, Moscow, 119071

A. A. Averin

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: vgrinberg@phyche.ac.ru
Russian Federation, Moscow, 119071

O. V. Bukhtenko

Topchiev Institute of Petrochemical Synthesis

Email: vgrinberg@phyche.ac.ru
Russian Federation, Moscow, 119991

D. A. Maslov

Topchiev Institute of Petrochemical Synthesis

Email: vgrinberg@phyche.ac.ru
Russian Federation, Moscow, 119991

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