Physicochemical properties of palladium adsorbents as catalysts in liquid-phase hydrogenation
- Authors: Efremov E.V.1, Filippov D.V.1, Barbov A.V.1
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Affiliations:
- Ivanovo State University of Chemistry and Technology
- Issue: Vol 52, No 3 (2016)
- Pages: 425-430
- Section: Physicochemical Processes at the Interfaces
- URL: https://journals.rcsi.science/2070-2051/article/view/202923
- DOI: https://doi.org/10.1134/S2070205116030072
- ID: 202923
Cite item
Abstract
The structure and physicochemical properties of palladium catalysts used in liquid-phase hydrogenation processes were studied with the use of adsorption, calorimetric, thermogravimetry, and temperature-programmed reduction techniques. The specific surface areas and average sizes and volume of pores of the adsorbents were determined. The palladium on activated carbon catalysts was found to possess a complex porous structure, whereas palladium on combined alumina and coal carrier catalysts is an adsorbent with a nonporous structure. The concentration of the applied metal and the nature of a support have a significant impact on the physicochemical properties of palladium catalysts.
About the authors
E. V. Efremov
Ivanovo State University of Chemistry and Technology
Author for correspondence.
Email: physchem@isuct.ru
Russian Federation, pr. Sheremetevskiy 7, Ivanovo, 153000
D. V. Filippov
Ivanovo State University of Chemistry and Technology
Email: physchem@isuct.ru
Russian Federation, pr. Sheremetevskiy 7, Ivanovo, 153000
A. V. Barbov
Ivanovo State University of Chemistry and Technology
Email: physchem@isuct.ru
Russian Federation, pr. Sheremetevskiy 7, Ivanovo, 153000
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