Physicochemical properties of palladium adsorbents as catalysts in liquid-phase hydrogenation


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Abstract

The structure and physicochemical properties of palladium catalysts used in liquid-phase hydrogenation processes were studied with the use of adsorption, calorimetric, thermogravimetry, and temperature-programmed reduction techniques. The specific surface areas and average sizes and volume of pores of the adsorbents were determined. The palladium on activated carbon catalysts was found to possess a complex porous structure, whereas palladium on combined alumina and coal carrier catalysts is an adsorbent with a nonporous structure. The concentration of the applied metal and the nature of a support have a significant impact on the physicochemical properties of palladium catalysts.

About the authors

E. V. Efremov

Ivanovo State University of Chemistry and Technology

Author for correspondence.
Email: physchem@isuct.ru
Russian Federation, pr. Sheremetevskiy 7, Ivanovo, 153000

D. V. Filippov

Ivanovo State University of Chemistry and Technology

Email: physchem@isuct.ru
Russian Federation, pr. Sheremetevskiy 7, Ivanovo, 153000

A. V. Barbov

Ivanovo State University of Chemistry and Technology

Email: physchem@isuct.ru
Russian Federation, pr. Sheremetevskiy 7, Ivanovo, 153000

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