Electrochemical investigation of inhibitory of new synthesized 3-(4-iodophenyl)-2-imino-2,3-dihydrobenzo[d]oxazol-5-yl 4-methylbenzenesulfonate on corrosion of al in acidic medium
- Authors: Ehsani A.1, Shiri H.M.2
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Affiliations:
- Department of Chemistry, Faculty of science
- Department of Chemistry
- Issue: Vol 52, No 2 (2016)
- Pages: 348-355
- Section: Physicochemical Problems of Materials Protection
- URL: https://journals.rcsi.science/2070-2051/article/view/202869
- DOI: https://doi.org/10.1134/S2070205116020088
- ID: 202869
Cite item
Abstract
3-(4-Iodophenyl)-2-imino-2,3-dihydrobenzo[d]oxazol-5-yl 4-methylbenzenesulfonate (4-IPhOXTs) was synthesized and its inhibiting action on the corrosion of Aluminum 1005 in sulfuric acid was investigated by means of potentiodynamic polarization and electrochemical impedance spectroscopy (EIS). The results of the investigation show that this compound has excellent inhibiting properties for Al corrosion in sulfuric acid. Inhibition efficiency increases with increase in the concentration of the inhibitor. The adsorption of 4-IPhOXTs onto the Al surface followed the Langmuir adsorption model with the free energy of adsorption ΔGads0 of‒9.18 kJ mol–1. Quantum chemical calculations were employed to give further insight into the mechanism of inhibition action of 4-IPhOXTs.
About the authors
Ali Ehsani
Department of Chemistry, Faculty of science
Author for correspondence.
Email: ehsani46847@yahoo.com
Iran, Islamic Republic of, Qom
Hamid Mohammad Shiri
Department of Chemistry
Author for correspondence.
Email: a.ehsani@qom.ac.ir
Iran, Islamic Republic of, Qom