Email this article Hydrogenation of Furfural to Furfuryl Alcohol in the Presence of Ru-Containing Catalysts Based on New Zeolite-Like Materials
- Authors: Kurchenko Y.V.1,2, Simakova I.L.2, Demidova Y.S.2, Panchenko V.N.1,2, Timofeeva M.N.1,2
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Affiliations:
- Novosibirsk State Technical University
- Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences
- Issue: Vol 11, No 2 (2019)
- Pages: 130-137
- Section: Catalysis in Chemical and Petrochemical Industry
- URL: https://journals.rcsi.science/2070-0504/article/view/203111
- DOI: https://doi.org/10.1134/S2070050419020065
- ID: 203111
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Abstract
Catalytic liquid-phase hydrogenation of furfural to commercially important furfuryl alcohol was studied in the presence of Ru-containing catalysts based on Sibunit and zeo-type materials, such as nickel phosphate molecular sieves (VSB-5 and Fe-VSB-5) and zirconium-containing metal–organic frameworks (UiO-66(Zr)-R, R = H and NH2), at 30 and 50°C and 5–25 atm of hydrogen. The yield of furfuryl alcohol was found to depend on the nature of the support and increases in the following order: Ru/UiO-66(Zr)-NH2 < Ru/UiO-66(Zr) < Ru/Fe-VSB-5 < Ru/VSB-5. The effect of hydrogen pressure and temperature on the selectivity toward furfuryl alcohol was investigated.
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About the authors
Yu. V. Kurchenko
Novosibirsk State Technical University; Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences
Email: simakova@catalysis.ru
Russian Federation, Novosibirsk, 630073; Novosibirsk, 630090
I. L. Simakova
Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences
Author for correspondence.
Email: simakova@catalysis.ru
Russian Federation, Novosibirsk, 630090
Yu. S. Demidova
Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences
Email: simakova@catalysis.ru
Russian Federation, Novosibirsk, 630090
V. N. Panchenko
Novosibirsk State Technical University; Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences
Email: simakova@catalysis.ru
Russian Federation, Novosibirsk, 630073; Novosibirsk, 630090
M. N. Timofeeva
Novosibirsk State Technical University; Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences
Email: simakova@catalysis.ru
Russian Federation, Novosibirsk, 630073; Novosibirsk, 630090
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