Experience in introducing a cobalt catalyst technology for the synthesis of hydrocarbons from CO and H2


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Abstract

The experience in introducing the technology of for the production of a silica-supported cobalt catalyst under industrial conditions is summarized. The catalyst is designed for the selective synthesis of С5+ hydrocarbons from СО and Н2, including macromolecular hydrocarbons С35+. The technology has been implemented at ZAO Samara Catalyst Factory. Parameters of the technological process are adjusted to allow for the features of existing equipment in preparing an experimental industrial lot of catalysts. The optimum technological mode of support preparation (evacuation to avoid granule cracking), its impregnation (at 80°С over 30 min), and the thermal treatment of the catalyst (in programmed mode at a maximum temperature of 400°С over a total of 9 h) are determined. The catalysts of an experimental industrial lot of 1 m3 conform to the new technical conditions in their physicochemical and catalytic properties.

About the authors

G. B. Narochnyi

Platov South Russian State Polytechnic University

Author for correspondence.
Email: narochgb@bk.ru
Russian Federation, Novocherkassk, 346428

R. E. Yakovenko

Platov South Russian State Polytechnic University

Email: narochgb@bk.ru
Russian Federation, Novocherkassk, 346428

A. P. Savost’yanov

Platov South Russian State Polytechnic University

Email: narochgb@bk.ru
Russian Federation, Novocherkassk, 346428

V. G. Bakun

Platov South Russian State Polytechnic University

Email: narochgb@bk.ru
Russian Federation, Novocherkassk, 346428

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