Studying the effect of process parameters on the epoxidation of propylene in a methanol medium in the presence of extruded titanium silicate
- Authors: Sulimov A.V.1, Danov S.M.1, Ovcharova A.V.1, Ovcharov A.A.1, Flid V.R.2
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Affiliations:
- Nizhny Novgorod State Technical University
- Moscow State University of Fine Chemical Technologies
- Issue: Vol 8, No 2 (2016)
- Pages: 116-120
- Section: Catalysis in Chemical and Petrochemical Industry
- URL: https://journals.rcsi.science/2070-0504/article/view/202190
- DOI: https://doi.org/10.1134/S2070050416020124
- ID: 202190
Cite item
Abstract
Quantitative data on the effect of process parameters on the main features of the liquid-phase epoxidation of propylene with an aqueous solution of hydrogen peroxide in the presence of extruded titanium silicate in a methanol medium are obtained. The effect of the solvent concentration (13.7–19.1 mol/L), the initial propylene: hydrogen peroxide ratio ((2–5) : 1), and the temperature (30–60°C) on the yield of the target product (propylene oxide) and such byproducts as 1,2-propyleneglycol, 1-methoxy-2-propanol, and 2-methoxy-1-propanol, is studied. The observed characteristics are used as a basis for recommendations concerning the conditions of propylene oxide synthesis in a continuous laboratory setup.
About the authors
A. V. Sulimov
Nizhny Novgorod State Technical University
Author for correspondence.
Email: epoxide@mail.ru
Russian Federation, Nizhny Novgorod, 603950
S. M. Danov
Nizhny Novgorod State Technical University
Email: epoxide@mail.ru
Russian Federation, Nizhny Novgorod, 603950
A. V. Ovcharova
Nizhny Novgorod State Technical University
Email: epoxide@mail.ru
Russian Federation, Nizhny Novgorod, 603950
A. A. Ovcharov
Nizhny Novgorod State Technical University
Email: epoxide@mail.ru
Russian Federation, Nizhny Novgorod, 603950
V. R. Flid
Moscow State University of Fine Chemical Technologies
Email: epoxide@mail.ru
Russian Federation, Moscow, 119571
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