Studying the effect of process parameters on the epoxidation of propylene in a methanol medium in the presence of extruded titanium silicate


Cite item

Full Text

Open Access Open Access
Restricted Access Access granted
Restricted Access Subscription Access

Abstract

Quantitative data on the effect of process parameters on the main features of the liquid-phase epoxidation of propylene with an aqueous solution of hydrogen peroxide in the presence of extruded titanium silicate in a methanol medium are obtained. The effect of the solvent concentration (13.7–19.1 mol/L), the initial propylene: hydrogen peroxide ratio ((2–5) : 1), and the temperature (30–60°C) on the yield of the target product (propylene oxide) and such byproducts as 1,2-propyleneglycol, 1-methoxy-2-propanol, and 2-methoxy-1-propanol, is studied. The observed characteristics are used as a basis for recommendations concerning the conditions of propylene oxide synthesis in a continuous laboratory setup.

About the authors

A. V. Sulimov

Nizhny Novgorod State Technical University

Author for correspondence.
Email: epoxide@mail.ru
Russian Federation, Nizhny Novgorod, 603950

S. M. Danov

Nizhny Novgorod State Technical University

Email: epoxide@mail.ru
Russian Federation, Nizhny Novgorod, 603950

A. V. Ovcharova

Nizhny Novgorod State Technical University

Email: epoxide@mail.ru
Russian Federation, Nizhny Novgorod, 603950

A. A. Ovcharov

Nizhny Novgorod State Technical University

Email: epoxide@mail.ru
Russian Federation, Nizhny Novgorod, 603950

V. R. Flid

Moscow State University of Fine Chemical Technologies

Email: epoxide@mail.ru
Russian Federation, Moscow, 119571

Supplementary files

Supplementary Files
Action
1. JATS XML

Copyright (c) 2016 Pleiades Publishing, Ltd.