Kinetic isotope H/D effect in the oxidation of ethers of linoleic acid in solutions

I. V. Tikhonov; I. V. Moskalenko; E. M. Pliss; M. A. Fomich; A. V. Bekish; V. V. Shmanai

doi:10.1134/S1990793117030113

Kinetic isotope H/D effect in the oxidation of ethers of linoleic acid in solutions

Autores: Tikhonov I.V.¹, Moskalenko I.V.¹, Pliss E.M.¹, Fomich M.A.², Bekish A.V.³, Shmanai V.V.²
Afiliações:
1. Demidov Yaroslavl University
2. Institute of Physical Organic Chemistry
3. Belarus State University
Edição: Volume 11, Nº 3 (2017)
Páginas: 395-399
Seção: Kinetics and Mechanism of Chemical Reactions. Catalysis
URL: https://journals.rcsi.science/1990-7931/article/view/199177
DOI: https://doi.org/10.1134/S1990793117030113
ID: 199177

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It is shown that the initiated oxidation of deuterated esters of linoleic acid proceeds as a radical chain process. The value of the kinetic isotope effect for hydrogen atom abstraction from the bisallyl group of linoleic acid esters is determined: 3.0 for tert-butyl peroxy and cumylperoxy radicals.