Effect of the electric potential of organoboron nanoparticles on their catalytic activity in the decomposition of ammonia
- 作者: Grishin M.V.1, Gatin A.K.1, Slutskii V.G.1, Kharitonov V.A.1, Tsyganov S.A.1, Shub B.R.1
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隶属关系:
- Semenov Institute of Chemical Physics
- 期: 卷 10, 编号 3 (2016)
- 页面: 538-542
- 栏目: Chemical Physics of Nanomaterials
- URL: https://journals.rcsi.science/1990-7931/article/view/197749
- DOI: https://doi.org/10.1134/S1990793116030192
- ID: 197749
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详细
For the first time, it has been shown that the rate of the catalytic decomposition of ammonia over (C2B10H4)n organoboron nanoparticles can be controlled via generating an electric potential of different polarity and magnitude on the particles using an external voltage source. At a temperature of 700 K, a pressure of 10–6 Torr, and a positive potential of the particles of +6 V, the decomposition rate increases by 26%, while at a negative potential of–6 V, it decreases by 37% compared to the decomposition rate of ammonia at a zero potential of the particles.
作者简介
M. Grishin
Semenov Institute of Chemical Physics
Email: slutsky@center.chph.ras.ru
俄罗斯联邦, Moscow
A. Gatin
Semenov Institute of Chemical Physics
Email: slutsky@center.chph.ras.ru
俄罗斯联邦, Moscow
V. Slutskii
Semenov Institute of Chemical Physics
编辑信件的主要联系方式.
Email: slutsky@center.chph.ras.ru
俄罗斯联邦, Moscow
V. Kharitonov
Semenov Institute of Chemical Physics
Email: slutsky@center.chph.ras.ru
俄罗斯联邦, Moscow
S. Tsyganov
Semenov Institute of Chemical Physics
Email: slutsky@center.chph.ras.ru
俄罗斯联邦, Moscow
B. Shub
Semenov Institute of Chemical Physics
Email: slutsky@center.chph.ras.ru
俄罗斯联邦, Moscow
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