Effect of the electric potential of organoboron nanoparticles on their catalytic activity in the decomposition of ammonia


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For the first time, it has been shown that the rate of the catalytic decomposition of ammonia over (C2B10H4)n organoboron nanoparticles can be controlled via generating an electric potential of different polarity and magnitude on the particles using an external voltage source. At a temperature of 700 K, a pressure of 10–6 Torr, and a positive potential of the particles of +6 V, the decomposition rate increases by 26%, while at a negative potential of–6 V, it decreases by 37% compared to the decomposition rate of ammonia at a zero potential of the particles.

作者简介

M. Grishin

Semenov Institute of Chemical Physics

Email: slutsky@center.chph.ras.ru
俄罗斯联邦, Moscow

A. Gatin

Semenov Institute of Chemical Physics

Email: slutsky@center.chph.ras.ru
俄罗斯联邦, Moscow

V. Slutskii

Semenov Institute of Chemical Physics

编辑信件的主要联系方式.
Email: slutsky@center.chph.ras.ru
俄罗斯联邦, Moscow

V. Kharitonov

Semenov Institute of Chemical Physics

Email: slutsky@center.chph.ras.ru
俄罗斯联邦, Moscow

S. Tsyganov

Semenov Institute of Chemical Physics

Email: slutsky@center.chph.ras.ru
俄罗斯联邦, Moscow

B. Shub

Semenov Institute of Chemical Physics

Email: slutsky@center.chph.ras.ru
俄罗斯联邦, Moscow

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