Superoxide radicals in the kinetics of nitroxide-inhibited oxidation of methyl linoleate in micelles


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The kinetics of the oxidation of methyl linoleate in micelles inhibited by stable nitroxides under the conditions of initiation by superoxide radicals was studied. Multiple breakdown of the oxidation chains was observed in this process. The antioxidant activity of nitroxides increased when the reduction potential of the oxoammonium cation/nitroxide pair decreased and their lipophilicity increased.

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E. Pliss

Demidov Yaroslavl State University

编辑信件的主要联系方式.
Email: e.pliss@mail.ru
俄罗斯联邦, Yaroslavl, 150000

L. Borodin

Demidov Yaroslavl State University

Email: e.pliss@mail.ru
俄罗斯联邦, Yaroslavl, 150000

V. Sen’

Demidov Yaroslavl State University; Institute of Problems of Chemical Physics

Email: e.pliss@mail.ru
俄罗斯联邦, Yaroslavl, 150000; Chernogolovka, Moscow oblast, 142432

I. Tikhonov

Demidov Yaroslavl State University

Email: e.pliss@mail.ru
俄罗斯联邦, Yaroslavl, 150000

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