Thermal Stimulation as a Prevailing Mechanism of Methane Conversion in Barrier Discharge
- 作者: Malanichev V.E.1,2, Malashin M.V.1, Popov V.E.1, Subbotin D.I.1,3, Surov A.V.1, Khomich V.Y.1, Shapovalova O.V.2, Shmelev V.M.2
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隶属关系:
- Institute for Electrophysics and Electric Power
- Semenov Institute of Chemical Physics
- St. Petersburg State Institute of Technology
- 期: 卷 12, 编号 6 (2018)
- 页面: 992-996
- 栏目: Kinetics and Mechanism of Chemical Reactions. Catalysis
- URL: https://journals.rcsi.science/1990-7931/article/view/201258
- DOI: https://doi.org/10.1134/S1990793118060076
- ID: 201258
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详细
The effect of energy deposition on the composition of the outlet mixture was studied in a plasmachemical reactor with barrier discharge. The composition of the conversion products was analyzed using a gas chromatograph and a quadrupole mass spectrometer. The process mainly occurred by the thermal mechanism of chain initiation and propagation. At an energy input of 3.25 eV/molecule, the selectivity for the main reaction products was 11.56% for acetylene, 14.76% for ethylene, 30.51% for ethane, 16.84% for propylene, 15.01% for propane, and 7.02% for hydrogen.
作者简介
V. Malanichev
Institute for Electrophysics and Electric Power; Semenov Institute of Chemical Physics
编辑信件的主要联系方式.
Email: mve.191@gmail.com
俄罗斯联邦, St. Petersburg, 191186; Moscow, 119991
M. Malashin
Institute for Electrophysics and Electric Power
Email: mve.191@gmail.com
俄罗斯联邦, St. Petersburg, 191186
V. Popov
Institute for Electrophysics and Electric Power
Email: mve.191@gmail.com
俄罗斯联邦, St. Petersburg, 191186
D. Subbotin
Institute for Electrophysics and Electric Power; St. Petersburg State Institute of Technology
Email: mve.191@gmail.com
俄罗斯联邦, St. Petersburg, 191186; St. Petersburg, 190013
A. Surov
Institute for Electrophysics and Electric Power
Email: mve.191@gmail.com
俄罗斯联邦, St. Petersburg, 191186
V. Khomich
Institute for Electrophysics and Electric Power
Email: mve.191@gmail.com
俄罗斯联邦, St. Petersburg, 191186
O. Shapovalova
Semenov Institute of Chemical Physics
Email: mve.191@gmail.com
俄罗斯联邦, Moscow, 119991
V. Shmelev
Semenov Institute of Chemical Physics
Email: mve.191@gmail.com
俄罗斯联邦, Moscow, 119991
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