Thermal Stimulation as a Prevailing Mechanism of Methane Conversion in Barrier Discharge


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The effect of energy deposition on the composition of the outlet mixture was studied in a plasmachemical reactor with barrier discharge. The composition of the conversion products was analyzed using a gas chromatograph and a quadrupole mass spectrometer. The process mainly occurred by the thermal mechanism of chain initiation and propagation. At an energy input of 3.25 eV/molecule, the selectivity for the main reaction products was 11.56% for acetylene, 14.76% for ethylene, 30.51% for ethane, 16.84% for propylene, 15.01% for propane, and 7.02% for hydrogen.

作者简介

V. Malanichev

Institute for Electrophysics and Electric Power; Semenov Institute of Chemical Physics

编辑信件的主要联系方式.
Email: mve.191@gmail.com
俄罗斯联邦, St. Petersburg, 191186; Moscow, 119991

M. Malashin

Institute for Electrophysics and Electric Power

Email: mve.191@gmail.com
俄罗斯联邦, St. Petersburg, 191186

V. Popov

Institute for Electrophysics and Electric Power

Email: mve.191@gmail.com
俄罗斯联邦, St. Petersburg, 191186

D. Subbotin

Institute for Electrophysics and Electric Power; St. Petersburg State Institute of Technology

Email: mve.191@gmail.com
俄罗斯联邦, St. Petersburg, 191186; St. Petersburg, 190013

A. Surov

Institute for Electrophysics and Electric Power

Email: mve.191@gmail.com
俄罗斯联邦, St. Petersburg, 191186

V. Khomich

Institute for Electrophysics and Electric Power

Email: mve.191@gmail.com
俄罗斯联邦, St. Petersburg, 191186

O. Shapovalova

Semenov Institute of Chemical Physics

Email: mve.191@gmail.com
俄罗斯联邦, Moscow, 119991

V. Shmelev

Semenov Institute of Chemical Physics

Email: mve.191@gmail.com
俄罗斯联邦, Moscow, 119991

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