Features of the kinetics of chemical reactions in a nanostructured liquid
- Authors: Kulagina T.P.1, Smirmov L.P.1
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Affiliations:
- Institute of Problems of Chemical Physics
- Issue: Vol 11, No 5 (2017)
- Pages: 786-797
- Section: Kinetics and Mechanism of Chemical Reactions. Catalysis
- URL: https://journals.rcsi.science/1990-7931/article/view/199621
- DOI: https://doi.org/10.1134/S1990793117050207
- ID: 199621
Cite item
Abstract
A review of the literature on the supramolecular structure of a liquid medium and the kinetics of formation of the structure has been presented. The models that relate the kinetics of chemical reactions to the liquid medium structure have been discussed. It has been shown that the results of the mathematical modeling of the kinetics of reactions in a nanostructured liquid medium taking into account the difference in the reactivity of molecules of the reagents and associates are consistent with the experimental data; in particular, they can be used to explain the cause of the observed kinetic anomalies.
About the authors
T. P. Kulagina
Institute of Problems of Chemical Physics
Author for correspondence.
Email: tan@icp.ac.ru
Russian Federation, Chernogolovka, Moscow oblast
L. P. Smirmov
Institute of Problems of Chemical Physics
Email: tan@icp.ac.ru
Russian Federation, Chernogolovka, Moscow oblast
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