A kinetic model of the reaction of dispersed aluminum with water under exposure to hydrocavitation and stabilization of the final product
- Авторы: Kolmakov K.M.1, Rozen A.E.1, Roshchin A.V.2, Panin E.O.2, Podval’nyi A.M.2
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Учреждения:
- Penza State University
- Semenov Institute of Chemical Physics
- Выпуск: Том 11, № 4 (2017)
- Страницы: 684-690
- Раздел: Chemical Physics of Ecological Processes
- URL: https://journals.rcsi.science/1990-7931/article/view/199504
- DOI: https://doi.org/10.1134/S1990793117040170
- ID: 199504
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Аннотация
The reaction of dispersed aluminum with water under the exposure of an A-IX-2 aluminum-containing explosive compound to hydrocavitation has been discussed. A kinetic model of the process has been developed; the chemical reaction rate constant has been determined under experimental conditions. It has been shown that the reaction occurs in an autocatalytic mode and can lead to the complete conversion of aluminum to aluminum hydroxide. A method to stabilize dispersed aluminum during the hydrocavitational extraction of a conversion explosive by using a phosphate buffer has been developed. Experiments have shown that the phosphate buffer has a stabilizing effect and leads to an improvement of the characteristics of the resulting industrial explosive composition.
Об авторах
K. Kolmakov
Penza State University
Автор, ответственный за переписку.
Email: voennii@list.ru
Россия, Penza
A. Rozen
Penza State University
Email: voennii@list.ru
Россия, Penza
A. Roshchin
Semenov Institute of Chemical Physics
Email: voennii@list.ru
Россия, Moscow
E. Panin
Semenov Institute of Chemical Physics
Email: voennii@list.ru
Россия, Moscow
A. Podval’nyi
Semenov Institute of Chemical Physics
Email: voennii@list.ru
Россия, Moscow
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