Fluctuation Anomalies of the Gravitational Center of the Raman Scattering OH Band in Water
- 作者: Pershin S.M.1, Grishin M.Y.1,2, Lednev V.N.1, Chizhov P.A.1
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隶属关系:
- Prokhorov General Physics Institute of the Russian Academy of Sciences
- Moscow Institute of Physics and Technology (State University)
- 期: 卷 27, 编号 2 (2019)
- 页面: 135-140
- 栏目: Terahertz and Optical Spectroscopy of Water and Aqueous Solutions
- URL: https://journals.rcsi.science/1541-308X/article/view/218178
- DOI: https://doi.org/10.3103/S1541308X19020080
- ID: 218178
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详细
Anomalously large fluctuations are experimentally found for the gravitational center of the OH band envelope of the Raman scattering of 10-ns pulses in water. Upon sensing of water with 15-ps pulses, OH band fluctuations multiply increase, which indicates existence of nonequilibrium processes at the finite lifetime of hydrogen bonds. Spectral density instabilities of OH oscillator states are analyzed using the model of fluctuations of the number of hydrogen bonds due to assumed formation/destruction of different-sized structural complexes in water.
作者简介
S. Pershin
Prokhorov General Physics Institute of the Russian Academy of Sciences
编辑信件的主要联系方式.
Email: pershin@kapella.gpi.ru
俄罗斯联邦, ul. Vavilova 38, Moscow, 119991
M. Grishin
Prokhorov General Physics Institute of the Russian Academy of Sciences; Moscow Institute of Physics and Technology (State University)
编辑信件的主要联系方式.
Email: mikhail.grishin@kapella.gpi.ru
俄罗斯联邦, ul. Vavilova 38, Moscow, 119991; Institutskiy per. 9, Dolgoprudny, Moscow oblast, 141701
V. Lednev
Prokhorov General Physics Institute of the Russian Academy of Sciences
编辑信件的主要联系方式.
Email: vas_ist_das@mail.ru
俄罗斯联邦, ul. Vavilova 38, Moscow, 119991
P. Chizhov
Prokhorov General Physics Institute of the Russian Academy of Sciences
编辑信件的主要联系方式.
Email: pvch@inbox.ru
俄罗斯联邦, ul. Vavilova 38, Moscow, 119991
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