Study of the Structure of Iron-Containing Zinc Borate Glass

A. A. Osipov; R. T. Zainullina; L. M. Osipova; M. V. Shtenberg; P. V. Khvorov; S. M. Lebedeva

doi:10.1134/S1087659618030112

Study of the Structure of Iron-Containing Zinc Borate Glass

Authors: Osipov A.A.¹, Zainullina R.T.¹, Osipova L.M.¹, Shtenberg M.V.¹, Khvorov P.V.¹, Lebedeva S.M.¹
Affiliations:
1. Institute of Mineralogy, Ural Branch
Issue: Vol 44, No 3 (2018)
Pages: 211-221
Section: Article
URL: https://journals.rcsi.science/1087-6596/article/view/216508
DOI: https://doi.org/10.1134/S1087659618030112
ID: 216508

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Abstract

The results of the experimental study of glass of the xFe₂O₃–(100–x)[40ZnO. 60B₂O₃] composition in which the content of iron oxide varies from 0 to 10 mol % are presented. The regularities of the glass structure change in the short- and intermediate-range order structures are considered based on the data of infrared spectroscopy and Raman spectroscopy. The valence and coordination state of iron in a glass matrix is studied by Mössbauer spectroscopy.