Volumetric nucleation of crystals catalyzed by Cr2O3 in glass based on furnace slags
- Авторы: Sycheva G.A.1, Polyakova I.G.1, Kostyreva T.G.1
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Учреждения:
- Grebenshchikov Institute of Silicate Chemistry
- Выпуск: Том 42, № 3 (2016)
- Страницы: 238-245
- Раздел: Article
- URL: https://journals.rcsi.science/1087-6596/article/view/215472
- DOI: https://doi.org/10.1134/S1087659616030147
- ID: 215472
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Аннотация
The features of the volumetric nucleation of crystals in glass obtained by melting furnace slags with the additive of SiO2, chromium sesquioxide Cr2O3, are studied by the methods of differential thermal and Xray phase analysis and optical microscopy. Upon the introduction of Cr2O3 as the catalytic additive, two phases are sequentially formed in the glass: magnesiochromite (MgO · Cr2O3) and diopside (CaO · MgO · 2SiO2). The characteristics of homogeneous and heterogeneous crystallization are determined: the stationary nucleation rate, nonstationary nucleation time, crystal growth rate, and their temperature dependences are obtained. Practical recommendations on the use of the obtained glass are given.
Об авторах
G. Sycheva
Grebenshchikov Institute of Silicate Chemistry
Автор, ответственный за переписку.
Email: sycheva_galina@mail.ru
Россия, nab. Makarova 2, St. Petersburg, 199034
I. Polyakova
Grebenshchikov Institute of Silicate Chemistry
Email: sycheva_galina@mail.ru
Россия, nab. Makarova 2, St. Petersburg, 199034
T. Kostyreva
Grebenshchikov Institute of Silicate Chemistry
Email: sycheva_galina@mail.ru
Россия, nab. Makarova 2, St. Petersburg, 199034
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