Electronic Spectra of Er(III) Ions in Sodium-Borate Melts


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In this work, the results of the spectral studies of xNa2O · (100 – x)B2O3 · Er2O3 (x = 0–45) melts at 1273 K are presented. When increasing the Na2O concentration in melts the cyclic changes of the coordination numbers of boron atoms are observed. It is shown that the coordination numbers of the Er(III) ions increase from 6 to 8 in the range from 0 to 12 mol % Na2O.

Sobre autores

A. Khokhryakov

Institute of Metallurgy, Ural Branch of Russian Academy of Sciences; Yeltsin Ural Federal University

Autor responsável pela correspondência
Email: 9221717036@mail.ru
Rússia, Yekaterinburg, 620014; Yekaterinburg, 620002

A. Paivin

Institute of Metallurgy, Ural Branch of Russian Academy of Sciences

Email: 9221717036@mail.ru
Rússia, Yekaterinburg, 620014

M. Samoilova

Institute of Metallurgy, Ural Branch of Russian Academy of Sciences

Email: 9221717036@mail.ru
Rússia, Yekaterinburg, 620014

V. Ryabov

Institute of Metallurgy, Ural Branch of Russian Academy of Sciences

Email: 9221717036@mail.ru
Rússia, Yekaterinburg, 620014

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