Parameters of the Porous Structure Formed as a Result of the Ion-Exchange Treatment of Potassium-Barium Silicate Glass in a Sodium Nitrate Melt


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Abstract

It is established by the method of standard porosimetry that glass with a porous structure is formed as a result of the \({\text{K}}_{{{\text{glass}}}}^{ + }~ \rightleftarrows ~{\text{Na}}_{{{\text{melt}}}}^{ \pm }\) ion exchange. Half of the porous glass structure volume is occupied by pores of 1 to 4 nm. The remaining volume is filled with pores and cracks of 0.4 to 3 μm. The porosity and specific surface area of meso- and macropores, as well as the average pore radius, are determined.

About the authors

S. I. Sviridov

Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences

Author for correspondence.
Email: sviridov@isc.nw.ru
Russian Federation, St. Petersburg, 199034

Z. G. Tyurnina

Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences

Email: sviridov@isc.nw.ru
Russian Federation, St. Petersburg, 199034

N. G. Tyurnina

Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences

Email: sviridov@isc.nw.ru
Russian Federation, St. Petersburg, 199034

V. V. Sirotov

Institute of Chemistry, Thermogravimetric and Calorimetric Studies Resource Center, St. Petersburg State University

Email: sviridov@isc.nw.ru
Russian Federation, St. Petersburg, 198504

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