Spectral Analysis of Ho3+ Doped Barium Zinc Boro-Tellurite Glasses for Yellow-Green Luminescent Applications
- Authors: Rajaramakrishna R.1, Wongdeeying C.1,2, Yasaka P.1,2, Limkitjaroenporn P.1,2, Kaewkhao J.1,2
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Affiliations:
- Centre of Excellence in Glass Technology and Materials Science, Nakhon Pathom Rajabhat University
- Physics Program, Faculty of Science and Technology, Nakhon Pathom Rajabhat University
- Issue: Vol 45, No 1 (2019)
- Pages: 29-35
- Section: Article
- URL: https://journals.rcsi.science/1087-6596/article/view/216981
- DOI: https://doi.org/10.1134/S1087659619010061
- ID: 216981
Cite item
Abstract
In this work, glasses of composition (30 – x)TeO2–30B2O3–10ZnO–30BaO–xHo2O3x = 0.00 0.05, 0.10, 0.50, 1.00, 1.50 mol % have been prepared through the melt quenching method. In order to characterize and explore their structural properties, we measured the density, refractive index of the glass which shows increasing trend with increase in Ho2O3 concentration also FTIR and XRD spectrum is used to study the structural properties of the developed glasses. XRD shows amorphous structure of the prepared glasses. FTIR shows B–O stretching (BO)3– units and Symmetrical stretching vibration of Te–O in TeO3. The electronic states belonging to the 4f configuration of trivalent Ho3+ were determined from the absorption spectra. Judd–Ofelt (JO) intensity analysis had been performed for oscillator strength and JO parameters were estimated to be Ω2 > Ω6 > Ω4. The emission spectra of the Ho doped glass samples were monitored at λexi = 454 nm. In the PL spectra, the characteristic emission bands due to f–f transition of Ho3+ were confirmed for the glass system, the transition 5I8 → 5G6 of Ho3+ ion is a hypersensitive transition and hence host dependent. For the transition 5F4 → 5I8 stimulated emission cross section is found to be 1.79 × 10–22 cm2.
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About the authors
R. Rajaramakrishna
Centre of Excellence in Glass Technology and Materials Science, Nakhon Pathom Rajabhat University
Author for correspondence.
Email: r.rajaramakrishna@gmail.com
Thailand, Nakhon Pathom, Meuang, 73000
C. Wongdeeying
Centre of Excellence in Glass Technology and Materials Science, Nakhon Pathom Rajabhat University; Physics Program, Faculty of Science and Technology, Nakhon Pathom Rajabhat University
Email: mink110@hotmail.com
Thailand, Nakhon Pathom, Meuang, 73000; Nakhon Pathom, 73000
P. Yasaka
Centre of Excellence in Glass Technology and Materials Science, Nakhon Pathom Rajabhat University; Physics Program, Faculty of Science and Technology, Nakhon Pathom Rajabhat University
Email: mink110@hotmail.com
Thailand, Nakhon Pathom, Meuang, 73000; Nakhon Pathom, 73000
P. Limkitjaroenporn
Centre of Excellence in Glass Technology and Materials Science, Nakhon Pathom Rajabhat University; Physics Program, Faculty of Science and Technology, Nakhon Pathom Rajabhat University
Email: mink110@hotmail.com
Thailand, Nakhon Pathom, Meuang, 73000; Nakhon Pathom, 73000
J. Kaewkhao
Centre of Excellence in Glass Technology and Materials Science, Nakhon Pathom Rajabhat University; Physics Program, Faculty of Science and Technology, Nakhon Pathom Rajabhat University
Author for correspondence.
Email: mink110@hotmail.com
Thailand, Nakhon Pathom, Meuang, 73000; Nakhon Pathom, 73000
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