Spectral Analysis of Ho3+ Doped Barium Zinc Boro-Tellurite Glasses for Yellow-Green Luminescent Applications


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Abstract

In this work, glasses of composition (30 – x)TeO2–30B2O3–10ZnO–30BaO–xHo2O3x = 0.00 0.05, 0.10, 0.50, 1.00, 1.50 mol % have been prepared through the melt quenching method. In order to characterize and explore their structural properties, we measured the density, refractive index of the glass which shows increasing trend with increase in Ho2O3 concentration also FTIR and XRD spectrum is used to study the structural properties of the developed glasses. XRD shows amorphous structure of the prepared glasses. FTIR shows B–O stretching (BO)3– units and Symmetrical stretching vibration of Te–O in TeO3. The electronic states belonging to the 4f configuration of trivalent Ho3+ were determined from the absorption spectra. Judd–Ofelt (JO) intensity analysis had been performed for oscillator strength and JO parameters were estimated to be Ω2 > Ω6 > Ω4. The emission spectra of the Ho doped glass samples were monitored at λexi = 454 nm. In the PL spectra, the characteristic emission bands due to f–f transition of Ho3+ were confirmed for the glass system, the transition 5I85G6 of Ho3+ ion is a hypersensitive transition and hence host dependent. For the transition 5F45I8 stimulated emission cross section is found to be 1.79 × 10–22 cm2.

About the authors

R. Rajaramakrishna

Centre of Excellence in Glass Technology and Materials Science, Nakhon Pathom Rajabhat University

Author for correspondence.
Email: r.rajaramakrishna@gmail.com
Thailand, Nakhon Pathom, Meuang, 73000

C. Wongdeeying

Centre of Excellence in Glass Technology and Materials Science, Nakhon Pathom Rajabhat University; Physics Program, Faculty of Science and Technology, Nakhon Pathom Rajabhat University

Email: mink110@hotmail.com
Thailand, Nakhon Pathom, Meuang, 73000; Nakhon Pathom, 73000

P. Yasaka

Centre of Excellence in Glass Technology and Materials Science, Nakhon Pathom Rajabhat University; Physics Program, Faculty of Science and Technology, Nakhon Pathom Rajabhat University

Email: mink110@hotmail.com
Thailand, Nakhon Pathom, Meuang, 73000; Nakhon Pathom, 73000

P. Limkitjaroenporn

Centre of Excellence in Glass Technology and Materials Science, Nakhon Pathom Rajabhat University; Physics Program, Faculty of Science and Technology, Nakhon Pathom Rajabhat University

Email: mink110@hotmail.com
Thailand, Nakhon Pathom, Meuang, 73000; Nakhon Pathom, 73000

J. Kaewkhao

Centre of Excellence in Glass Technology and Materials Science, Nakhon Pathom Rajabhat University; Physics Program, Faculty of Science and Technology, Nakhon Pathom Rajabhat University

Author for correspondence.
Email: mink110@hotmail.com
Thailand, Nakhon Pathom, Meuang, 73000; Nakhon Pathom, 73000

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