Neodymium nickelate—A cathode material for fuel cells


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Abstract

Nanocrystals of the neodymium nickelate (Nd2NiO4) compound have been synthesized using the method of the combined crystallization of nitrates’ solutions and its electrophysical properties have been investigated. It has been established that Nd2NiO4 is characterized with rather high specific conductivity of the metallic type (∼200 S cm–1) in the temperature range 500–900°C and the thermal expansion coefficient comparable with that of solid solutions based on ZrO2.

About the authors

L. V. Morozova

Grebenshchikov Institute of Silicate Chemistry

Author for correspondence.
Email: morozova_l_v@mail.ru
Russian Federation, nab. Makarova 2, St. Petersburg, 199034

M. V. Kalinina

Grebenshchikov Institute of Silicate Chemistry

Email: morozova_l_v@mail.ru
Russian Federation, nab. Makarova 2, St. Petersburg, 199034

M. Yu. Arsent’ev

Grebenshchikov Institute of Silicate Chemistry

Email: morozova_l_v@mail.ru
Russian Federation, nab. Makarova 2, St. Petersburg, 199034

V. P. Popov

Grebenshchikov Institute of Silicate Chemistry

Email: morozova_l_v@mail.ru
Russian Federation, nab. Makarova 2, St. Petersburg, 199034

I. A. Drozdova

Grebenshchikov Institute of Silicate Chemistry

Email: morozova_l_v@mail.ru
Russian Federation, nab. Makarova 2, St. Petersburg, 199034

I. G. Polyakova

Grebenshchikov Institute of Silicate Chemistry

Email: morozova_l_v@mail.ru
Russian Federation, nab. Makarova 2, St. Petersburg, 199034

O. A. Shilova

Grebenshchikov Institute of Silicate Chemistry

Email: morozova_l_v@mail.ru
Russian Federation, nab. Makarova 2, St. Petersburg, 199034

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