Synthesis of ethyl (2 E ,4 E )- and (2 E ,4 Z )-5-chloropenta-2,4-dienoates

R. N. Shakhmaev; A. Sh. Sunagatullina; D. A. Akimova; V. V. Zorin

doi:10.1134/S1070428017040194

Synthesis of ethyl (2E,4E)- and (2E,4Z)-5-chloropenta-2,4-dienoates

作者: Shakhmaev R.N.¹, Sunagatullina A.S.¹, Akimova D.A.¹, Zorin V.V.¹
隶属关系:
1. Ufa State Petroleum Technological University
期: 卷 53, 编号 4 (2017)
页面: 615-617
栏目: Short Communications
URL: https://journals.rcsi.science/1070-4280/article/view/216123
DOI: https://doi.org/10.1134/S1070428017040194
ID: 216123

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详细

An efficient synthetic approach to 2E,4E and 2E,4Z isomers of ethyl 5-chloropenta-2,4-dienoate has been developed on the basis of one-pot oxidation–olefination of readily accessible (E)- and (Z)-3-chloroprop-2-en-1-ols by the action of barium manganate and ethyl (triphenyl-λ⁵-phosphanylidene)acetate.