电邮这篇文章 Synthesis of chloropolyfluoroarenes from polyfluoroarenethiols and PCl5
- 作者: Nikul’shin P.V.1, Maksimov А.M.1, Platonov V.Е.1
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隶属关系:
- Vorozhtsov Novosibirsk Institute of Organic Chemistry
- 期: 卷 52, 编号 2 (2016)
- 页面: 200-205
- 栏目: Article
- URL: https://journals.rcsi.science/1070-4280/article/view/213681
- DOI: https://doi.org/10.1134/S1070428016020068
- ID: 213681
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详细
Replacement of the thiol group in polyfluoroarenethiols with chlorine was performed by treating with PCl5 as chlorinating agent. By heating in ampules at 200–220°C polyfluoro- and polyfluorochloroarenethiols with PCl5 mono- and dichloropolyfluoroarenes and also 1,2,4-trifluorotrichlorobenzene were synthesized. Dichloropolyfluoroarenes contain chlorine atoms in ortho- and para-positions.
作者简介
P. Nikul’shin
Vorozhtsov Novosibirsk Institute of Organic Chemistry
Email: platonov@nioch.nsc.ru
俄罗斯联邦, pr. Academika Lavrent’eva 9, Novosibirsk, 630090
А. Maksimov
Vorozhtsov Novosibirsk Institute of Organic Chemistry
Email: platonov@nioch.nsc.ru
俄罗斯联邦, pr. Academika Lavrent’eva 9, Novosibirsk, 630090
V. Platonov
Vorozhtsov Novosibirsk Institute of Organic Chemistry
编辑信件的主要联系方式.
Email: platonov@nioch.nsc.ru
俄罗斯联邦, pr. Academika Lavrent’eva 9, Novosibirsk, 630090
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