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Synthesis of 1-organyl-1-(trimethylsiloxy)-2-(dimethylamino)ethenes and new hypervalent silicon compounds based thereon


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Resumo

1-Organyl-1-(trimethylsiloxy)-2-(dimethylamino)ethenes were synthesized for the first time, and their reactions with trichloro(methyl)silane and trifluoro(phenyl)silane afforded silicon bis-chelates, methylbis-[2-(dimethylamino)-1-(organyl)ethenolato-N,O]siliconium chlorides and bis[1-(dimethylamino)-3,3-dimethylbut-1-en-2-olato-N,O]fluoro(phenyl)silicon(IV), respectively.

Sobre autores

B. Gostevskii

Favorskii Irkutsk Institute of Chemistry, Siberian Branch

Autor responsável pela correspondência
Email: gost_bgu@irioch.irk.ru
Rússia, ul. Favorskogo 1, Irkutsk, 664033

A. Albanov

Favorskii Irkutsk Institute of Chemistry, Siberian Branch

Email: gost_bgu@irioch.irk.ru
Rússia, ul. Favorskogo 1, Irkutsk, 664033

A. Vashchenko

Favorskii Irkutsk Institute of Chemistry, Siberian Branch

Email: gost_bgu@irioch.irk.ru
Rússia, ul. Favorskogo 1, Irkutsk, 664033

V. Smirnov

Favorskii Irkutsk Institute of Chemistry, Siberian Branch

Email: gost_bgu@irioch.irk.ru
Rússia, ul. Favorskogo 1, Irkutsk, 664033

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