Synthesis of 2-(12-aryldodecanoyl)cyclohexane-1,3-diones


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Synthesis was developed of 2-(10-undecenoyl)cyclohexane-1,3-diones containing in the side chain keto and hydroxy groups and a phenyl substituent. The synthesis is underlain by a nitrile oxide approach. The scheme included isoxazole synthesis for the protection of the β,β′-tricarbonyl fragment, building up of a heterocycle by 1,3-dipolar cycloaddition of nitrile oxide in situ to the terminal double bond, cycle opening (of isoxazole and isoxazoline), and alkaline hydrolysis.

Sobre autores

N. Vasilyeva

M. Tank Belarus State Pedagogical University

Autor responsável pela correspondência
Email: ogeiko@rambler.ru
Belarus, Sovetskaya ul. 18, Minsk, 220030

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