Trifluoromethanesulfonic acid in organic synthesis


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Аннотация

The review analyzes data published in the past decade on the use of trifluoromethanesulfonic acid (triflic acid, CF3SO3H, TfOH) in organic synthesis, in particular in electrophilic aromatic substitution (Friedel–Crafts) reactions, formation of carbon–carbon and carbon–heteroatom bonds, isomerizations, syntheses of carboand heterocyclic structures, and other reactions, as well as in natural and organometallic compounds chemistry. The high protonating power and low nucleophilicity makes trifluoromethanesulfonic acid capable of generating from organic molecules cationic species which can be detected by spectral methods (NMR, IR spectroscopy, etc.), and their transformations can be studied. Experimental simplicity and efficiency of reactions promoted by trifluoromethanesulfonic acid make it a convenient reagent for the synthesis of new organic compounds.

Авторлар туралы

A. Kazakova

St. Petersburg State University

Email: aleksvasil@mail.ru
Ресей, Universitetskii pr. 26, St. Petersburg, 198504

A. Vasilyev

St. Petersburg State University; St. Petersburg State Forest Technical University

Хат алмасуға жауапты Автор.
Email: aleksvasil@mail.ru
Ресей, Universitetskii pr. 26, St. Petersburg, 198504; Institutskii per. 5, St. Petersburg, 194021

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