Enviar artigo por via de e-mail Formation of 1-aminophenazine from 3,4-dihydrophenazin-1(2H)-one oxime in the system acetylene–KOH–DMSO
- Autores: Petrova O.V.1, Sobenina L.N.1, Budaev A.B.1, Ivanov A.V.1, Samsonov V.A.2, Tikhonov A.Y.2, Trofimov B.A.1
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Afiliações:
- Favorskii Irkutsk Institute of Chemistry, Siberian Branch
- Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch
- Edição: Volume 53, Nº 1 (2017)
- Páginas: 150-152
- Seção: Short Communications
- URL: https://journals.rcsi.science/1070-4280/article/view/215721
- DOI: https://doi.org/10.1134/S1070428017010316
- ID: 215721
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Resumo
The reaction of 3,4-dihydrophenazin-1(2H)-one oxime with acetylene in the superbasic system KOH–DMSO afforded 1-aminophenazine in 32% yield instead of the expected pyrrolophenazine. The same product was also obtained under analogous conditions in the absence of acetylene.
Sobre autores
O. Petrova
Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Email: boris_trofimov@irioch.irk.ru
Rússia, ul. Favorskogo 1, Irkutsk, 664033
L. Sobenina
Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Email: boris_trofimov@irioch.irk.ru
Rússia, ul. Favorskogo 1, Irkutsk, 664033
A. Budaev
Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Email: boris_trofimov@irioch.irk.ru
Rússia, ul. Favorskogo 1, Irkutsk, 664033
A. Ivanov
Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Email: boris_trofimov@irioch.irk.ru
Rússia, ul. Favorskogo 1, Irkutsk, 664033
V. Samsonov
Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch
Email: boris_trofimov@irioch.irk.ru
Rússia, pr. Akademika Lavrent’eva 9, Novosibirsk, 630090
A. Tikhonov
Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch
Email: boris_trofimov@irioch.irk.ru
Rússia, pr. Akademika Lavrent’eva 9, Novosibirsk, 630090
B. Trofimov
Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Autor responsável pela correspondência
Email: boris_trofimov@irioch.irk.ru
Rússia, ul. Favorskogo 1, Irkutsk, 664033
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