Regio- and Stereoselective Addition of Selenium Dichloride to Alkyl Propiolates

M. V. Musalov; V. A. Yakimov; V. A. Potapov; M. V. Andreev; S. V. Amosova

doi:10.1134/S1070428019110277

Regio- and Stereoselective Addition of Selenium Dichloride to Alkyl Propiolates

作者: Musalov M.V.¹, Yakimov V.A.¹, Potapov V.A.¹, Andreev M.V.¹, Amosova S.V.¹
隶属关系:
1. Favorskii Irkutsk Institute of Chemistry, Siberian Branch
期: 卷 55, 编号 11 (2019)
页面: 1809-1811
栏目: Short Communications
URL: https://journals.rcsi.science/1070-4280/article/view/221436
DOI: https://doi.org/10.1134/S1070428019110277
ID: 221436

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详细

The reaction of selenium dichloride with methyl and ethyl propiolates leads to formation of anti-Markovnikov adducts. The regio- and stereoselective synthesis of hitherto unknown bis[(E)-2-chloro-1-(alkoxycarbonyl)vinyl]selenides has been developed based on this reaction.