电邮这篇文章 Oxidative transformations of alkyl caryophyllanyl sulfides
- 作者: Gyrdymova Y.V.1, Sudarikov D.V.1, Rubtsova S.A.1, Kutchin A.V.1
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隶属关系:
- Institute of Chemistry, Komi Scientific Center, Ural Branch
- 期: 卷 53, 编号 6 (2017)
- 页面: 853-859
- 栏目: Article
- URL: https://journals.rcsi.science/1070-4280/article/view/216337
- DOI: https://doi.org/10.1134/S1070428017060070
- ID: 216337
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详细
Sesquiterpene sulfoxides and sulfones were synthesized in up to 56 and 74% yields, respectively. The oxidation of sulfides was accompanied by rearrangement of the epoxide fragment to allylic alcohol with subsequent oxidation. The isomerization of 4,5-epoxycaryophyllane-15-thiol afforded for the first time 4,11,11-trimethyl-8-(sulfanylmethyl)bicyclo[7.2.0]undec-3-en-5-ol in 40–45% yield.
作者简介
Yu. Gyrdymova
Institute of Chemistry, Komi Scientific Center, Ural Branch
编辑信件的主要联系方式.
Email: gyrdymova-jw@chemi.komisc.ru
俄罗斯联邦, ul. Pervomaiskaya 48, Syktyvkar, 167000
D. Sudarikov
Institute of Chemistry, Komi Scientific Center, Ural Branch
Email: gyrdymova-jw@chemi.komisc.ru
俄罗斯联邦, ul. Pervomaiskaya 48, Syktyvkar, 167000
S. Rubtsova
Institute of Chemistry, Komi Scientific Center, Ural Branch
Email: gyrdymova-jw@chemi.komisc.ru
俄罗斯联邦, ul. Pervomaiskaya 48, Syktyvkar, 167000
A. Kutchin
Institute of Chemistry, Komi Scientific Center, Ural Branch
Email: gyrdymova-jw@chemi.komisc.ru
俄罗斯联邦, ul. Pervomaiskaya 48, Syktyvkar, 167000
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