Synthesis of 1-organyl-1-(trimethylsiloxy)-2-(dimethylamino)ethenes and new hypervalent silicon compounds based thereon

B. A. Gostevskii; A. I. Albanov; A. V. Vashchenko; V. I. Smirnov

doi:10.1134/S107042801610002X

Synthesis of 1-organyl-1-(trimethylsiloxy)-2-(dimethylamino)ethenes and new hypervalent silicon compounds based thereon

Авторлар: Gostevskii B.A.¹, Albanov A.I.¹, Vashchenko A.V.¹, Smirnov V.I.¹
Мекемелер:
1. Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Шығарылым: Том 52, № 10 (2016)
Беттер: 1385-1389
Бөлім: Article
URL: https://journals.rcsi.science/1070-4280/article/view/215008
DOI: https://doi.org/10.1134/S107042801610002X
ID: 215008

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Аннотация

1-Organyl-1-(trimethylsiloxy)-2-(dimethylamino)ethenes were synthesized for the first time, and their reactions with trichloro(methyl)silane and trifluoro(phenyl)silane afforded silicon bis-chelates, methylbis-[2-(dimethylamino)-1-(organyl)ethenolato-N,O]siliconium chlorides and bis[1-(dimethylamino)-3,3-dimethylbut-1-en-2-olato-N,O]fluoro(phenyl)silicon(IV), respectively.