Email this article Reaction of N,N′-Methylenebis(trifluoromethanesulfonamide) with Styrene under Oxidative Conditions
- Authors: Moskalik M.Y.1, Astakhova V.V.1, Ganin A.S.1, Shainyan B.A.1
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Affiliations:
- Favorskii Irkutsk Institute of Chemistry, Siberian Branch
- Issue: Vol 55, No 5 (2019)
- Pages: 734-736
- Section: Short Communications
- URL: https://journals.rcsi.science/1070-4280/article/view/220688
- DOI: https://doi.org/10.1134/S1070428019050270
- ID: 220688
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Abstract
The reaction of N,N′-methylenebis(trifluoromethanesulfonamide) with styrene in the oxidative system t-BuOCl/NaI affords triflamide, 2-iodo-1-phenylethanol, N,N′-bis(trifluoromethanesulfonyl)urea, and the product of styrene bistriflamidation. The mechanism is proposed involving hydrolysis and oxidation of the starting N,N′-methylenebis(trifluoromethanesulfonamide).
About the authors
M. Yu. Moskalik
Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Email: bagrat@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033
V. V. Astakhova
Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Email: bagrat@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033
A. S. Ganin
Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Email: bagrat@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033
B. A. Shainyan
Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Author for correspondence.
Email: bagrat@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033
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