Formation of a Cluster H2V10O284– under the Action of Brønsted Acids and Its Catalytic Activity in Oxidation of Alkylbenzenes
- 作者: Ul’yanova M.I.1, Pervova M.G.1, Slepukhin P.A.1,2, Aksenova T.V.2, Pestov A.V.1,2
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隶属关系:
- Postovskii Institute of Organic Synthesis, Ural Branch
- Ural Federal University named after the First President of Russia B.N. Yeltsin
- 期: 卷 54, 编号 5 (2018)
- 页面: 687-690
- 栏目: Article
- URL: https://journals.rcsi.science/1070-4280/article/view/217730
- DOI: https://doi.org/10.1134/S1070428018050020
- ID: 217730
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详细
New method was developed for the preparation of vanadium cluster of the composition {Me2NH2}4* H2V10O28 from vanadyl(IV) acetylacetonate in the presence of 2-hydroxy-2-trifluoromethylchroman-4-one or its synthetic precursor, 2′-hydroxyacetophenone. The structure of the cluster was proved by X-ray diffraction (XRD) analysis. The cluster of decavanadate catalyzes oxidation of toluene and o-xylene creating promising situation for developing new catalytic materials.
作者简介
M. Ul’yanova
Postovskii Institute of Organic Synthesis, Ural Branch
Email: pestov@ios.uran.ru
俄罗斯联邦, ul. S. Kovalevskoi/Academicheskaya 22/20, Yekaterinburg, 620137
M. Pervova
Postovskii Institute of Organic Synthesis, Ural Branch
Email: pestov@ios.uran.ru
俄罗斯联邦, ul. S. Kovalevskoi/Academicheskaya 22/20, Yekaterinburg, 620137
P. Slepukhin
Postovskii Institute of Organic Synthesis, Ural Branch; Ural Federal University named after the First President of Russia B.N. Yeltsin
Email: pestov@ios.uran.ru
俄罗斯联邦, ul. S. Kovalevskoi/Academicheskaya 22/20, Yekaterinburg, 620137; Yekaterinburg, 620002
T. Aksenova
Ural Federal University named after the First President of Russia B.N. Yeltsin
Email: pestov@ios.uran.ru
俄罗斯联邦, Yekaterinburg, 620002
A. Pestov
Postovskii Institute of Organic Synthesis, Ural Branch; Ural Federal University named after the First President of Russia B.N. Yeltsin
编辑信件的主要联系方式.
Email: pestov@ios.uran.ru
俄罗斯联邦, ul. S. Kovalevskoi/Academicheskaya 22/20, Yekaterinburg, 620137; Yekaterinburg, 620002
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